Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]2+{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}

Wai Hong Fung; Wing Chi Cheng; Wing Yiu Yu; Chi Ming Che; Thomas C.W. Mak

doi:10.1039/C39950002007

Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]²⁺{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}

Wai Hong Fung
, Wing Chi Cheng
, Wing Yiu Yu
, Chi Ming Che
, Thomas C.W. Mak

Research output: Journal article publication › Journal article › Academic research › peer-review

41 Citations (Scopus)

Abstract

A new chiral monooxoruthenium(IV) complex containing 2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine and 2,2′-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2precusor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.

Original language	English
Pages (from-to)	2007-2008
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39950002007
Publication status	Published - 1 Dec 1995
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39950002007

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Fung, W. H., Cheng, W. C., Yu, W. Y., Che, C. M., & Mak, T. C. W. (1995). Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]²⁺{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}. Journal of the Chemical Society, Chemical Communications, (19), 2007-2008. https://doi.org/10.1039/C39950002007

Fung, Wai Hong ; Cheng, Wing Chi ; Yu, Wing Yiu et al. / Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]²⁺{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}. In: Journal of the Chemical Society, Chemical Communications. 1995 ; No. 19. pp. 2007-2008.

@article{14f27cd99e744536a3b7e50ddaaf70a1,

title = "Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]2+\{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine\}",

abstract = "A new chiral monooxoruthenium(IV) complex containing 2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine and 2,2′-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2precusor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.",

author = "Fung, \{Wai Hong\} and Cheng, \{Wing Chi\} and Yu, \{Wing Yiu\} and Che, \{Chi Ming\} and Mak, \{Thomas C.W.\}",

year = "1995",

month = dec,

day = "1",

doi = "10.1039/C39950002007",

language = "English",

pages = "2007--2008",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "19",

}

Fung, WH, Cheng, WC, Yu, WY, Che, CM & Mak, TCW 1995, 'Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]²⁺{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}', Journal of the Chemical Society, Chemical Communications, no. 19, pp. 2007-2008. https://doi.org/10.1039/C39950002007

Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]²⁺{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}. / Fung, Wai Hong; Cheng, Wing Chi; Yu, Wing Yiu et al.
In: Journal of the Chemical Society, Chemical Communications, No. 19, 01.12.1995, p. 2007-2008.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]2+{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}

AU - Fung, Wai Hong

AU - Cheng, Wing Chi

AU - Yu, Wing Yiu

AU - Che, Chi Ming

AU - Mak, Thomas C.W.

PY - 1995/12/1

Y1 - 1995/12/1

N2 - A new chiral monooxoruthenium(IV) complex containing 2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine and 2,2′-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2precusor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.

AB - A new chiral monooxoruthenium(IV) complex containing 2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine and 2,2′-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2precusor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.

UR - https://www.scopus.com/pages/publications/37049084311

U2 - 10.1039/C39950002007

DO - 10.1039/C39950002007

M3 - Journal article

SN - 0022-4936

SP - 2007

EP - 2008

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 19

ER -

Fung WH, Cheng WC, Yu WY, Che CM, Mak TCW. Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]²⁺{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}. Journal of the Chemical Society, Chemical Communications. 1995 Dec 1;(19):2007-2008. doi: 10.1039/C39950002007