TY - JOUR
T1 - Enantioselective epoxidation of unfunctionalized alkenes by a chiral monooxoruthenium(IV) complex [RuL(bpy)O]2+{L=2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine; Bpy=2,2′-bipyridine}
AU - Fung, Wai Hong
AU - Cheng, Wing Chi
AU - Yu, Wing Yiu
AU - Che, Chi Ming
AU - Mak, Thomas C.W.
PY - 1995/12/1
Y1 - 1995/12/1
N2 - A new chiral monooxoruthenium(IV) complex containing 2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine and 2,2′-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2precusor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.
AB - A new chiral monooxoruthenium(IV) complex containing 2,6-bis[(4S,7R)-7,8,8- trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl]pyridine and 2,2′-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2precusor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.
UR - http://www.scopus.com/inward/record.url?scp=37049084311&partnerID=8YFLogxK
U2 - 10.1039/C39950002007
DO - 10.1039/C39950002007
M3 - Journal article
SN - 0022-4936
SP - 2007
EP - 2008
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 19
ER -