Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine

Kwong Chak Cheung; Peng Guo; Ming Him So; Yoon Suk Lee; Kam Piu Ho; Wing Leung Wong; Kam Han Lee; Wing Tak Wong; Zhong Yuan Zhou; Kwok Yin Wong

doi:10.1016/j.jorganchem.2009.04.034

Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine

Kwong Chak Cheung
, Peng Guo
, Ming Him So
, Yoon Suk Lee
, Kam Piu Ho
, Wing Leung Wong
, Kam Han Lee
, Wing Tak Wong
, Zhong Yuan Zhou
, Kwok Yin Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

34 Citations (Scopus)

Abstract

A dipyridylamine ligand with a pendant pyrrole (N-(3-N,N′-bis(2-pyridyl)propylamino)pyrrole, PPP) and its corresponding rhenium(I) complex, Re(CO)3(κ2-N,N-PPP)Cl, were synthesized. The structure of Re(CO)3(κ2-N,N-PPP)Cl was determined by X-ray crystallography. Electrochemical polymerization of the pyrrole moiety resulted in the immobilization of poly[Re(CO)3(κ2-N,N-PPP)Cl] film onto a glassy carbon electrode, which exhibited electrocatalytic activity for the reduction of CO2to CO.

Original language	English
Pages (from-to)	2842-2845
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	694
Issue number	17
DOIs	https://doi.org/10.1016/j.jorganchem.2009.04.034
Publication status	Published - 1 Aug 2009

Keywords

Carbon dioxide
Electrocatalysis
Polypyrrole films
Rhenium complex

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/j.jorganchem.2009.04.034

Cite this

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title = "Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine",

abstract = "A dipyridylamine ligand with a pendant pyrrole (N-(3-N,N′-bis(2-pyridyl)propylamino)pyrrole, PPP) and its corresponding rhenium(I) complex, Re(CO)3(κ2-N,N-PPP)Cl, were synthesized. The structure of Re(CO)3(κ2-N,N-PPP)Cl was determined by X-ray crystallography. Electrochemical polymerization of the pyrrole moiety resulted in the immobilization of poly[Re(CO)3(κ2-N,N-PPP)Cl] film onto a glassy carbon electrode, which exhibited electrocatalytic activity for the reduction of CO2to CO.",

keywords = "Carbon dioxide, Electrocatalysis, Polypyrrole films, Rhenium complex",

author = "Cheung, \{Kwong Chak\} and Peng Guo and So, \{Ming Him\} and Lee, \{Yoon Suk\} and Ho, \{Kam Piu\} and Wong, \{Wing Leung\} and Lee, \{Kam Han\} and Wong, \{Wing Tak\} and Zhou, \{Zhong Yuan\} and Wong, \{Kwok Yin\}",

year = "2009",

month = aug,

day = "1",

doi = "10.1016/j.jorganchem.2009.04.034",

language = "English",

volume = "694",

pages = "2842--2845",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine

AU - Cheung, Kwong Chak

AU - Guo, Peng

AU - So, Ming Him

AU - Lee, Yoon Suk

AU - Ho, Kam Piu

AU - Wong, Wing Leung

AU - Lee, Kam Han

AU - Wong, Wing Tak

AU - Zhou, Zhong Yuan

AU - Wong, Kwok Yin

PY - 2009/8/1

Y1 - 2009/8/1

N2 - A dipyridylamine ligand with a pendant pyrrole (N-(3-N,N′-bis(2-pyridyl)propylamino)pyrrole, PPP) and its corresponding rhenium(I) complex, Re(CO)3(κ2-N,N-PPP)Cl, were synthesized. The structure of Re(CO)3(κ2-N,N-PPP)Cl was determined by X-ray crystallography. Electrochemical polymerization of the pyrrole moiety resulted in the immobilization of poly[Re(CO)3(κ2-N,N-PPP)Cl] film onto a glassy carbon electrode, which exhibited electrocatalytic activity for the reduction of CO2to CO.

AB - A dipyridylamine ligand with a pendant pyrrole (N-(3-N,N′-bis(2-pyridyl)propylamino)pyrrole, PPP) and its corresponding rhenium(I) complex, Re(CO)3(κ2-N,N-PPP)Cl, were synthesized. The structure of Re(CO)3(κ2-N,N-PPP)Cl was determined by X-ray crystallography. Electrochemical polymerization of the pyrrole moiety resulted in the immobilization of poly[Re(CO)3(κ2-N,N-PPP)Cl] film onto a glassy carbon electrode, which exhibited electrocatalytic activity for the reduction of CO2to CO.

KW - Carbon dioxide

KW - Electrocatalysis

KW - Polypyrrole films

KW - Rhenium complex

UR - https://www.scopus.com/pages/publications/67650091544

U2 - 10.1016/j.jorganchem.2009.04.034

DO - 10.1016/j.jorganchem.2009.04.034

M3 - Journal article

SN - 0022-328X

VL - 694

SP - 2842

EP - 2845

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 17

ER -

Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine

Abstract

Keywords

ASJC Scopus subject areas

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