Efficient dehalogenation of polyhalomethanes and production of strong acids in aqueous environments: Water-catalyzed O-H-insertion and HI-elimination reactions of isodiiodomethane (CH2I-I) with water

Wai Ming Kwok, Cunyuan Zhao, Xiangguo Guan, Yun Liang Li, Yong Du, David Lee Phillips

Research output: Journal article publicationJournal articleAcademic researchpeer-review

25 Citations (Scopus)

Abstract

The ultraviolet photolysis of polyhalomethanes such as CH2I2in water was investigated. The gas and solution pa\hse picosecond time-resolved resonance Raman spectroscopy was used for the study. It was observed that ultraviolet photolysis of CH2I2led to almost complete conversion into CH2(OH)2and 2HI products. It was also found that the photolysis at low concentration led to efficient dehalogenation as well as release of multiple strong acid (HI) leaving groups.
Original languageEnglish
Pages (from-to)9017-9032
Number of pages16
JournalJournal of Chemical Physics
Volume120
Issue number19
DOIs
Publication statusPublished - 15 May 2004
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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