Effects of Post-Flame Fuel Injection on the Destruction of Chlorinated Hydrocarbons

S. Lee; C. P. Koshland; R. F. Sawyer; D. Lucas

doi:10.1080/00102209408951875

Effects of Post-Flame Fuel Injection on the Destruction of Chlorinated Hydrocarbons

S. Lee, C. P. Koshland, R. F. Sawyer, D. Lucas

Research output: Journal article publication › Journal article › Academic research › peer-review

1 Citation (Scopus)

Abstract

The effects of post-flame fuel injection on the destruction of chlorinated hydrocarbons has been studied in a combustion flow reactor. All three fuels studied (CH₄, C₂H₆, and CO) enhance the destruction of CH₃C1. CO is the only effective post-flame fuel for the destruction of C₂H₅Cl, and none of the fuels improve the destruction of 1, 1, 1-C₂H₃C1₃. These results are explained by considering the destruction mechanisms: unimolecular reactions are not influenced by fuel addition, and bimolecular reactions involving radicals can be enhanced or inhibited, depending on the nature of both the fuel and CHC,.

Original language	English
Pages (from-to)	247-260
Number of pages	14
Journal	Combustion Science and Technology
Volume	101
Issue number	1-6
DOIs	https://doi.org/10.1080/00102209408951875
Publication status	Published - 1 Nov 1994
Externally published	Yes

Keywords

and inhibition
chlorinated hydrocarbons
enhancement
fuel injection
incineration
Post-flame combustion

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology
General Physics and Astronomy

More information

10.1080/00102209408951875

Cite this

@article{672e8366c4e74454bed927ec65aacedb,

title = "Effects of Post-Flame Fuel Injection on the Destruction of Chlorinated Hydrocarbons",

abstract = "The effects of post-flame fuel injection on the destruction of chlorinated hydrocarbons has been studied in a combustion flow reactor. All three fuels studied (CH4, C2H6, and CO) enhance the destruction of CH3C1. CO is the only effective post-flame fuel for the destruction of C2H5Cl, and none of the fuels improve the destruction of 1, 1, 1-C2H3C13. These results are explained by considering the destruction mechanisms: unimolecular reactions are not influenced by fuel addition, and bimolecular reactions involving radicals can be enhanced or inhibited, depending on the nature of both the fuel and CHC,.",

keywords = "and inhibition, chlorinated hydrocarbons, enhancement, fuel injection, incineration, Post-flame combustion",

author = "S. Lee and Koshland, {C. P.} and Sawyer, {R. F.} and D. Lucas",

year = "1994",

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AU - Lee, S.

AU - Koshland, C. P.

AU - Sawyer, R. F.

AU - Lucas, D.

PY - 1994/11/1

Y1 - 1994/11/1

N2 - The effects of post-flame fuel injection on the destruction of chlorinated hydrocarbons has been studied in a combustion flow reactor. All three fuels studied (CH4, C2H6, and CO) enhance the destruction of CH3C1. CO is the only effective post-flame fuel for the destruction of C2H5Cl, and none of the fuels improve the destruction of 1, 1, 1-C2H3C13. These results are explained by considering the destruction mechanisms: unimolecular reactions are not influenced by fuel addition, and bimolecular reactions involving radicals can be enhanced or inhibited, depending on the nature of both the fuel and CHC,.

AB - The effects of post-flame fuel injection on the destruction of chlorinated hydrocarbons has been studied in a combustion flow reactor. All three fuels studied (CH4, C2H6, and CO) enhance the destruction of CH3C1. CO is the only effective post-flame fuel for the destruction of C2H5Cl, and none of the fuels improve the destruction of 1, 1, 1-C2H3C13. These results are explained by considering the destruction mechanisms: unimolecular reactions are not influenced by fuel addition, and bimolecular reactions involving radicals can be enhanced or inhibited, depending on the nature of both the fuel and CHC,.

KW - and inhibition

KW - chlorinated hydrocarbons

KW - enhancement

KW - fuel injection

KW - incineration

KW - Post-flame combustion

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DO - 10.1080/00102209408951875

M3 - Journal article

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JO - Combustion Science and Technology

JF - Combustion Science and Technology

IS - 1-6

ER -

Effects of Post-Flame Fuel Injection on the Destruction of Chlorinated Hydrocarbons

Abstract

Keywords

ASJC Scopus subject areas

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