Disproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous medium

Kwok Yin Wong; Chi Ming Che; Wai Hing Yip; Ru Ji Wang; Thomas C.W. Mak

doi:10.1039/DT9920001417

Disproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous medium

Kwok Yin Wong
, Chi Ming Che
, Wai Hing Yip
, Ru Ji Wang
, Thomas C.W. Mak

Research output: Journal article publication › Journal article › Academic research › peer-review

24 Citations (Scopus)

Abstract

The reaction of trans-[RuLCl2]+(L = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) with NO2-in water at 60 °C leads to the formation of trans-[RuL(O)Cl]+and trans-[RuL(OH)(NO)]2+. The formation of the products can be rationalized by the disproportionation of trans-[RuL(Cl)(NO2)]+. The structures of the products have been determined by X-ray crystallography: trans-[RuL(O)Cl]ClO4, space group Pna21(no. 33), a = 12.616(1), b = 15.421(3), c = 11.292(3) Å; Ru=O and Ru-Cl 1.75(1) and 2.435(6) Å; trans-[RuL(OH)(NO)][ClO4]2, space group Pbca (no. 61), a = 20.459(3), b = 29.16(1), c = 25.13(1) Å; average Ru-OH and Ru-NO 1.906(9) and 1.74(1) Å.

Original language	English
Pages (from-to)	1417-1421
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	8
DOIs	https://doi.org/10.1039/DT9920001417
Publication status	Published - 1 Dec 1992
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/DT9920001417

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@article{c404e893ee7942adbf478cd2a377d196,

title = "Disproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous medium",

abstract = "The reaction of trans-[RuLCl2]+(L = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) with NO2-in water at 60 °C leads to the formation of trans-[RuL(O)Cl]+and trans-[RuL(OH)(NO)]2+. The formation of the products can be rationalized by the disproportionation of trans-[RuL(Cl)(NO2)]+. The structures of the products have been determined by X-ray crystallography: trans-[RuL(O)Cl]ClO4, space group Pna21(no. 33), a = 12.616(1), b = 15.421(3), c = 11.292(3) {\AA}; Ru=O and Ru-Cl 1.75(1) and 2.435(6) {\AA}; trans-[RuL(OH)(NO)][ClO4]2, space group Pbca (no. 61), a = 20.459(3), b = 29.16(1), c = 25.13(1) {\AA}; average Ru-OH and Ru-NO 1.906(9) and 1.74(1) {\AA}.",

author = "Wong, \{Kwok Yin\} and Che, \{Chi Ming\} and Yip, \{Wai Hing\} and Wang, \{Ru Ji\} and Mak, \{Thomas C.W.\}",

year = "1992",

month = dec,

day = "1",

doi = "10.1039/DT9920001417",

language = "English",

pages = "1417--1421",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Disproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous medium

AU - Wong, Kwok Yin

AU - Che, Chi Ming

AU - Yip, Wai Hing

AU - Wang, Ru Ji

AU - Mak, Thomas C.W.

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The reaction of trans-[RuLCl2]+(L = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) with NO2-in water at 60 °C leads to the formation of trans-[RuL(O)Cl]+and trans-[RuL(OH)(NO)]2+. The formation of the products can be rationalized by the disproportionation of trans-[RuL(Cl)(NO2)]+. The structures of the products have been determined by X-ray crystallography: trans-[RuL(O)Cl]ClO4, space group Pna21(no. 33), a = 12.616(1), b = 15.421(3), c = 11.292(3) Å; Ru=O and Ru-Cl 1.75(1) and 2.435(6) Å; trans-[RuL(OH)(NO)][ClO4]2, space group Pbca (no. 61), a = 20.459(3), b = 29.16(1), c = 25.13(1) Å; average Ru-OH and Ru-NO 1.906(9) and 1.74(1) Å.

AB - The reaction of trans-[RuLCl2]+(L = 1,5,9,13-tetramethyl-1,5,9,13-tetraazacyclohexadecane) with NO2-in water at 60 °C leads to the formation of trans-[RuL(O)Cl]+and trans-[RuL(OH)(NO)]2+. The formation of the products can be rationalized by the disproportionation of trans-[RuL(Cl)(NO2)]+. The structures of the products have been determined by X-ray crystallography: trans-[RuL(O)Cl]ClO4, space group Pna21(no. 33), a = 12.616(1), b = 15.421(3), c = 11.292(3) Å; Ru=O and Ru-Cl 1.75(1) and 2.435(6) Å; trans-[RuL(OH)(NO)][ClO4]2, space group Pbca (no. 61), a = 20.459(3), b = 29.16(1), c = 25.13(1) Å; average Ru-OH and Ru-NO 1.906(9) and 1.74(1) Å.

UR - https://www.scopus.com/pages/publications/37049067653

U2 - 10.1039/DT9920001417

DO - 10.1039/DT9920001417

M3 - Journal article

SN - 1472-7773

SP - 1417

EP - 1421

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 8

ER -

Disproportionation of a ruthenium(III) nitro complex of a macrocyclic tertiary amine in an aqueous medium

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