Direct observation of the 4-methoxyphenylnitrene intersystem crossing from S1 to T1 using picosecond kerr-gated time-resolved resonance Raman spectroscopy

Wai Ming Kwok; Pik Ying Chan; David Lee Phillips

doi:10.1021/jp044670t

Direct observation of the 4-methoxyphenylnitrene intersystem crossing from S₁ to T₁ using picosecond kerr-gated time-resolved resonance Raman spectroscopy

Wai Ming Kwok, Pik Ying Chan, David Lee Phillips

Research output: Journal article publication › Journal article › Academic research › peer-review

10 Citations (Scopus)

Abstract

A picosecond Kerr-gated time-resolved resonance Raman (ps-KTR3) study of the singlet 4-methoxyphenyl-nitrene intersystem crossing to produce the triplet 4-methoxyphenylnitrene species is reported. The experimental resonance Raman vibrational band frequencies observed for the singlet and triplet 4-methoxylphenylnitrene species in the time-resolved Raman experiments are compared to each other and to predictions from previously published density functional theory calculations. The structure, properties, and chemical reactivity of the singlet and triplet states of the 4-methoxyphenylnitrenes are briefly discussed.

Original language	English
Pages (from-to)	2394-2400
Number of pages	7
Journal	Journal of Physical Chemistry A
Volume	109
Issue number	10
DOIs	https://doi.org/10.1021/jp044670t
Publication status	Published - 17 Mar 2005
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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10.1021/jp044670t

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title = "Direct observation of the 4-methoxyphenylnitrene intersystem crossing from S1 to T1 using picosecond kerr-gated time-resolved resonance Raman spectroscopy",

abstract = "A picosecond Kerr-gated time-resolved resonance Raman (ps-KTR3) study of the singlet 4-methoxyphenyl-nitrene intersystem crossing to produce the triplet 4-methoxyphenylnitrene species is reported. The experimental resonance Raman vibrational band frequencies observed for the singlet and triplet 4-methoxylphenylnitrene species in the time-resolved Raman experiments are compared to each other and to predictions from previously published density functional theory calculations. The structure, properties, and chemical reactivity of the singlet and triplet states of the 4-methoxyphenylnitrenes are briefly discussed.",

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Direct observation of the 4-methoxyphenylnitrene intersystem crossing from S₁ to T₁ using picosecond kerr-gated time-resolved resonance Raman spectroscopy. / Kwok, Wai Ming; Chan, Pik Ying; Phillips, David Lee.
In: Journal of Physical Chemistry A, Vol. 109, No. 10, 17.03.2005, p. 2394-2400.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

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AU - Chan, Pik Ying

AU - Phillips, David Lee

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AB - A picosecond Kerr-gated time-resolved resonance Raman (ps-KTR3) study of the singlet 4-methoxyphenyl-nitrene intersystem crossing to produce the triplet 4-methoxyphenylnitrene species is reported. The experimental resonance Raman vibrational band frequencies observed for the singlet and triplet 4-methoxylphenylnitrene species in the time-resolved Raman experiments are compared to each other and to predictions from previously published density functional theory calculations. The structure, properties, and chemical reactivity of the singlet and triplet states of the 4-methoxyphenylnitrenes are briefly discussed.

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U2 - 10.1021/jp044670t

DO - 10.1021/jp044670t

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JF - Journal of Physical Chemistry A

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ER -

Direct observation of the 4-methoxyphenylnitrene intersystem crossing from S₁ to T₁ using picosecond kerr-gated time-resolved resonance Raman spectroscopy

Abstract

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