Direct observation of intrinsic twin domains in tetragonal !CH3NH3PbI3

Mathias Uller Rothmann, Wei Li, Ye Zhu, Udo Bach, Leone Spiccia, Joanne Etheridge, Yi Bing Cheng

Research output: Journal article publicationJournal articleAcademic researchpeer-review

182 Citations (Scopus)


Organic-inorganic hybrid perovskites are exciting candidates for next-generation solar cells, with CH3NH3PbI3being one of the most widely studied. While there have been intense efforts to fabricate and optimize photovoltaic devices using CH3NH3PbI3, critical questions remain regarding the crystal structure that governs its unique properties of the hybrid perovskite material. Here we report unambiguous evidence for crystallographic twin domains in tetragonal CH3NH3PbI3, observed using low-dose transmission electron microscopy and selected area electron diffraction. The domains are around 100-300 nm wide, which disappear/reappear above/below the tetragonal-to-cubic phase transition temperature (approximate 57 °C) in a reversible process that often 'memorizes'the scale and orientation of the domains. Since these domains exist within the operational temperature range of solar cells, and have dimensions comparable to the thickness of typical CH3NH3PbI3films in the solar cells, understanding the twin geometry and orientation is essential for further improving perovskite solar cells.
Original languageEnglish
Article number14547
JournalNature Communications
Publication statusPublished - 23 Feb 2017
Externally publishedYes

ASJC Scopus subject areas

  • General Chemistry
  • General Biochemistry,Genetics and Molecular Biology
  • General Physics and Astronomy


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