Diastereoselective formation of a dicopper(i) helicate with a chiral tetradentate pyridylthiazole ligand

Chui Shan Tsang, Ho Lun Yeung, Wing Tak Wong, Hoi Lun Kwong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

17 Citations (Scopus)

Abstract

Reaction of a pinene-based pyridylthioamide with 1,4-dibromo-2,3- butanedione in refluxing methanol yielded a new chiral pyridylthiazole ligand L which forms a dinuclear double-stranded helicate with Cu(i) ions; this helicate has opposite helical chirality when compared with its quaterpyridine analogue.
Original languageEnglish
Pages (from-to)1999-2001
Number of pages3
JournalChemical Communications
Issue number15
DOIs
Publication statusPublished - 10 Apr 2009
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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