Diamine complexes of nickel(II) nitrate: X-ray single crystal structural analysis of trans-[NiL2(NO3)2] [L = 1-(2-aminoethyl)piperidine]

Inamur R. Laskar; Debasis Das; Wing Tak Wong; N. Ray Chaudhuri

doi:10.1023/A:1011003029546

Diamine complexes of nickel(II) nitrate: X-ray single crystal structural analysis of trans-[NiL₂(NO₃)₂] [L = 1-(2-aminoethyl)piperidine]

Inamur R. Laskar, Debasis Das, Wing Tak Wong, N. Ray Chaudhuri

Research output: Journal article publication › Journal article › Academic research › peer-review

1 Citation (Scopus)

Abstract

Trans-[NiL2(H2O)2](NO3)2(pale blue) (1), trans-[NiL2(NO3)2] (dark blue) (2)**, [L = 1-(2-aminoethyl)piperidine] and trans-[NiL′2(H2O)2](NO3)2(blue) (3) [L = 1-(2-aminoethyl)pyrrolidine] have been prepared. Complexes (1) and (3) upon heating undergo deaquation-anation yielding trans-[NiL2(NO3)2] (dark blue) (2) and cis-[NiL′2(NO3)](NO3) (blue) (3a), respectively. The X-ray single crystal structure of complex (2) has been determined.

Original language	English
Pages (from-to)	594-597
Number of pages	4
Journal	Transition Metal Chemistry
Volume	26
Issue number	4-5
DOIs	https://doi.org/10.1023/A:1011003029546
Publication status	Published - 1 Aug 2001
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

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10.1023/A:1011003029546

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@article{98135effd1544193b2311d6a3dc073ac,

title = "Diamine complexes of nickel(II) nitrate: X-ray single crystal structural analysis of trans-[NiL2(NO3)2] [L = 1-(2-aminoethyl)piperidine]",

abstract = "Trans-[NiL2(H2O)2](NO3)2(pale blue) (1), trans-[NiL2(NO3)2] (dark blue) (2)**, [L = 1-(2-aminoethyl)piperidine] and trans-[NiL′2(H2O)2](NO3)2(blue) (3) [L = 1-(2-aminoethyl)pyrrolidine] have been prepared. Complexes (1) and (3) upon heating undergo deaquation-anation yielding trans-[NiL2(NO3)2] (dark blue) (2) and cis-[NiL′2(NO3)](NO3) (blue) (3a), respectively. The X-ray single crystal structure of complex (2) has been determined.",

author = "Laskar, \{Inamur R.\} and Debasis Das and Wong, \{Wing Tak\} and Chaudhuri, \{N. Ray\}",

year = "2001",

month = aug,

day = "1",

doi = "10.1023/A:1011003029546",

language = "English",

volume = "26",

pages = "594--597",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "4-5",

}

Diamine complexes of nickel(II) nitrate: X-ray single crystal structural analysis of trans-[NiL₂(NO₃)₂] [L = 1-(2-aminoethyl)piperidine]. / Laskar, Inamur R.; Das, Debasis; Wong, Wing Tak et al.
In: Transition Metal Chemistry, Vol. 26, No. 4-5, 01.08.2001, p. 594-597.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Diamine complexes of nickel(II) nitrate: X-ray single crystal structural analysis of trans-[NiL2(NO3)2] [L = 1-(2-aminoethyl)piperidine]

AU - Laskar, Inamur R.

AU - Das, Debasis

AU - Wong, Wing Tak

AU - Chaudhuri, N. Ray

PY - 2001/8/1

Y1 - 2001/8/1

N2 - Trans-[NiL2(H2O)2](NO3)2(pale blue) (1), trans-[NiL2(NO3)2] (dark blue) (2)**, [L = 1-(2-aminoethyl)piperidine] and trans-[NiL′2(H2O)2](NO3)2(blue) (3) [L = 1-(2-aminoethyl)pyrrolidine] have been prepared. Complexes (1) and (3) upon heating undergo deaquation-anation yielding trans-[NiL2(NO3)2] (dark blue) (2) and cis-[NiL′2(NO3)](NO3) (blue) (3a), respectively. The X-ray single crystal structure of complex (2) has been determined.

AB - Trans-[NiL2(H2O)2](NO3)2(pale blue) (1), trans-[NiL2(NO3)2] (dark blue) (2)**, [L = 1-(2-aminoethyl)piperidine] and trans-[NiL′2(H2O)2](NO3)2(blue) (3) [L = 1-(2-aminoethyl)pyrrolidine] have been prepared. Complexes (1) and (3) upon heating undergo deaquation-anation yielding trans-[NiL2(NO3)2] (dark blue) (2) and cis-[NiL′2(NO3)](NO3) (blue) (3a), respectively. The X-ray single crystal structure of complex (2) has been determined.

UR - https://www.scopus.com/pages/publications/0035426575

U2 - 10.1023/A:1011003029546

DO - 10.1023/A:1011003029546

M3 - Journal article

SN - 0340-4285

VL - 26

SP - 594

EP - 597

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 4-5

ER -

Diamine complexes of nickel(II) nitrate: X-ray single crystal structural analysis of trans-[NiL₂(NO₃)₂] [L = 1-(2-aminoethyl)piperidine]

Abstract

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