Diamine complexes of nickel(II) nitrate: X-ray single crystal structural analysis of trans-[NiL2(NO3)2] [L = 1-(2-aminoethyl)piperidine]

Inamur R. Laskar, Debasis Das, Wing Tak Wong, N. Ray Chaudhuri

Research output: Journal article publicationJournal articleAcademic researchpeer-review

1 Citation (Scopus)

Abstract

Trans-[NiL2(H2O)2](NO3)2(pale blue) (1), trans-[NiL2(NO3)2] (dark blue) (2)**, [L = 1-(2-aminoethyl)piperidine] and trans-[NiL′2(H2O)2](NO3)2(blue) (3) [L = 1-(2-aminoethyl)pyrrolidine] have been prepared. Complexes (1) and (3) upon heating undergo deaquation-anation yielding trans-[NiL2(NO3)2] (dark blue) (2) and cis-[NiL′2(NO3)](NO3) (blue) (3a), respectively. The X-ray single crystal structure of complex (2) has been determined.
Original languageEnglish
Pages (from-to)594-597
Number of pages4
JournalTransition Metal Chemistry
Volume26
Issue number4-5
DOIs
Publication statusPublished - 1 Aug 2001
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Metals and Alloys
  • Materials Chemistry

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