@article{3a47544c907b49f4bfff0f285d6d2848,
title = "Design of Benzimidazolyl Phosphines Bearing AlterableP,OorP,N-Coordination: Synthesis, Characterization, and Insights into Their Reactivity",
abstract = "A new series of hemilabile benzimidazolyl phosphines is reported. Entities in this ligand family can be easily assembled and prepared on a large scale via a simple one-pot procedure. X-ray crystallographic analyses show that the Pd metal center can coordinate in different fashions, where it relies on the size of the −PR2group. With the same ligand scaffold, the ligand having a −PCy2moiety displays better efficiency in expediting aromatic C-C bond-coupling reactions, while the ligand associated with a −P-t-Bu2group, in contrast, promotes C-N bond-forming reactions.",
author = "Wong, {Shun Man} and Choy, {Pui Ying} and Qingyang Zhao and Yuen, {On Ying} and Yeung, {Chung Chiu} and So, {Chau Ming} and Kwong, {Fuk Yee}",
note = "Funding Information: This paper is dedicated to Prof. Albert S. C. Chan on the occasion of his 70th birthday. We thank the Research Grants Council of Hong Kong (GRF: 14304519-19P), and CUHK Direct Grants (4053388 and 4442353) for financial support. We are grateful for financial support from the Innovation and Technology Commission (HKSAR, China) to the State Key Laboratory of Synthetic Chemistry. We are grateful to Prof. Zhongyuan Zhou (PolyU) for X-ray analysis, Dr. Yun Wei (Anhui Normal University) and Dr. Wesley Ting Kwok Chan (PolyU) for X-ray refinement, Dr. Pui Kin So (University Facilities in Life Science, PolyU) for HRMS analysis, and Ms. Man Yee Ho for NMR analysis. Publisher Copyright: {\textcopyright} 2021 American Chemical Society",
year = "2021",
month = jul,
day = "26",
doi = "10.1021/acs.organomet.0c00816",
language = "English",
volume = "40",
pages = "2265--2271",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "14",
}