TY - JOUR
T1 - Design and Assessment of a Novel Cogeneration Process of Synthetic Natural Gas and Char via Biomass Pyrolysis-Coupled Hydrothermal Gasification
AU - Song, Guohui
AU - Zhao, Liang
AU - Zhao, Hao
AU - Xiao, Jun
AU - Wang, Hongyan
AU - Guo, Shuqing
N1 - Funding Information:
This work was financially supported by the Scientific Foundation of Nanjing Institute of Technology (YKJ201818). The first author gratefully acknowledges the financial support from the China Scholarship Council (201908320106).
Publisher Copyright:
© 2020 American Chemical Society.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2021
Y1 - 2021
N2 - To simultaneously produce synthetic natural gas (SNG) and char from biomass, this paper proposed a novel cogeneration process via pyrolysis-coupled hydrothermal gasification. Two typical process configurations were designed and modeled by Aspen Plus. A mathematical model of bio-oil composition involving varieties of typical organic components was established by digging experimental data and then integrated into the Aspen Plus platform, which can describe the biomass pyrolysis process better. Taking SNG as the main product, this work focused on the effects of pyrolysis temperature, hydrothermal gasification temperature and pressure, and feedstock concentration on the composition and yield of SNG as well as energy efficiencies. The results show that the pyrolysis temperature significantly affects the yields of SNG and char, as well as energy efficiencies. Subsequently, the composition and yield of SNG are quite sensitive to the hydrothermal gasification temperature. Then, the hydrothermal gasification pressure has little influence on all process indicators. Finally, the feedstock concentration only has a small effect on CH4 concentration and SNG yield. By application of the flexible operation modules of the cogeneration process, bio-oil can be potentially used as the carrier for seasonal energy storage. This cogeneration process can be regarded as a new approach to upgrade and utilize raw bio-oil.
AB - To simultaneously produce synthetic natural gas (SNG) and char from biomass, this paper proposed a novel cogeneration process via pyrolysis-coupled hydrothermal gasification. Two typical process configurations were designed and modeled by Aspen Plus. A mathematical model of bio-oil composition involving varieties of typical organic components was established by digging experimental data and then integrated into the Aspen Plus platform, which can describe the biomass pyrolysis process better. Taking SNG as the main product, this work focused on the effects of pyrolysis temperature, hydrothermal gasification temperature and pressure, and feedstock concentration on the composition and yield of SNG as well as energy efficiencies. The results show that the pyrolysis temperature significantly affects the yields of SNG and char, as well as energy efficiencies. Subsequently, the composition and yield of SNG are quite sensitive to the hydrothermal gasification temperature. Then, the hydrothermal gasification pressure has little influence on all process indicators. Finally, the feedstock concentration only has a small effect on CH4 concentration and SNG yield. By application of the flexible operation modules of the cogeneration process, bio-oil can be potentially used as the carrier for seasonal energy storage. This cogeneration process can be regarded as a new approach to upgrade and utilize raw bio-oil.
UR - http://www.scopus.com/inward/record.url?scp=85098796176&partnerID=8YFLogxK
U2 - 10.1021/acs.iecr.0c04504
DO - 10.1021/acs.iecr.0c04504
M3 - Journal article
AN - SCOPUS:85098796176
JO - Industrial & Engineering Chemistry Research
JF - Industrial & Engineering Chemistry Research
SN - 0888-5885
ER -