Delton communications. Synthesis and characterization of a palladium-osmium mixed-metal cluster; Crystal structure of [os6Pd(CO)18(bipy)]·CHCl3(bipy = 2,2′-bipyridine)

Suzanna Chan; Wing Tak Wong

doi:10.1039/DT9940001605

Delton communications. Synthesis and characterization of a palladium-osmium mixed-metal cluster; Crystal structure of [os₆Pd(CO)₁₈(bipy)]·CHCl₃(bipy = 2,2′-bipyridine)

Suzanna Chan
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

18 Citations (Scopus)

Abstract

The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.

Original language	English
Pages (from-to)	1605-1606
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/DT9940001605
Publication status	Published - 1 Dec 1994
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1039/DT9940001605

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title = "Delton communications. Synthesis and characterization of a palladium-osmium mixed-metal cluster; Crystal structure of [os6Pd(CO)18(bipy)]·CHCl3(bipy = 2,2′-bipyridine)",

abstract = "The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.",

author = "Suzanna Chan and Wong, \{Wing Tak\}",

year = "1994",

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doi = "10.1039/DT9940001605",

language = "English",

pages = "1605--1606",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "10",

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Delton communications. Synthesis and characterization of a palladium-osmium mixed-metal cluster; Crystal structure of [os₆Pd(CO)₁₈(bipy)]·CHCl₃(bipy = 2,2′-bipyridine). / Chan, Suzanna; Wong, Wing Tak.
In: Journal of the Chemical Society, Dalton Transactions, No. 10, 01.12.1994, p. 1605-1606.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

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AU - Wong, Wing Tak

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.

AB - The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.

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DO - 10.1039/DT9940001605

M3 - Journal article

SN - 1472-7773

SP - 1605

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JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

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Delton communications. Synthesis and characterization of a palladium-osmium mixed-metal cluster; Crystal structure of [os₆Pd(CO)₁₈(bipy)]·CHCl₃(bipy = 2,2′-bipyridine)

Abstract

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