TY - JOUR
T1 - Delton communications. Synthesis and characterization of a palladium-osmium mixed-metal cluster; Crystal structure of [os6Pd(CO)18(bipy)]·CHCl3(bipy = 2,2′-bipyridine)
AU - Chan, Suzanna
AU - Wong, Wing Tak
PY - 1994/12/1
Y1 - 1994/12/1
N2 - The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.
AB - The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.
UR - http://www.scopus.com/inward/record.url?scp=37049079734&partnerID=8YFLogxK
U2 - 10.1039/DT9940001605
DO - 10.1039/DT9940001605
M3 - Journal article
SN - 1472-7773
SP - 1605
EP - 1606
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 10
ER -