Delton communications. Synthesis and characterization of a palladium-osmium mixed-metal cluster; Crystal structure of [os6Pd(CO)18(bipy)]·CHCl3(bipy = 2,2′-bipyridine)

Suzanna Chan, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

18 Citations (Scopus)

Abstract

The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2′-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy)(CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.
Original languageEnglish
Pages (from-to)1605-1606
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number10
DOIs
Publication statusPublished - 1 Dec 1994
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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