Dawson-type polyoxometalate-based oligomeric Hg(II)-acetylide hybrid: Synthesis, characterization and materials properties

Li Liu, Lei Hu, Qian Liu, Shi Zhong Liu, Fa Bao Li, Ling Li, Liang Peng, Deng Hui Yao, Wai Yeung Wong, Zu Liang Du

Research output: Journal article publicationJournal articleAcademic researchpeer-review

3 Citations (Scopus)

Abstract

Abstract A new synthetic scheme for preparing Dawson-type polyoxometalate (POM) based inorganic-organic hybrid material is reported. A new heteropolytungstate-based oligomeric Hg(II) acetylide inorganic-organic hybrid compound (OHgOD) was prepared by Hagihara's dehydrohalogenating coupling of a diacetylene POM hybrid with diphosphoryl functionality and mercury(II) halide. This method provides a rigid covalent linkage between the POM and the organometallic Hg(II) acetylide moiety. The materials properties of hybrid LB film derived from the hybrid were studied.
Original languageEnglish
Article number18940
Pages (from-to)102-108
Number of pages7
JournalJournal of Organometallic Chemistry
Volume792
DOIs
Publication statusPublished - 23 Dec 2015
Externally publishedYes

Keywords

  • Acetylide
  • Inorganic-organic hybrid
  • LB film
  • Mercury
  • Polyoxometalate

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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