Dalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)4{(μ- Hg)Os3(CO)10(μ-η2-CH=CHPh)} 2] and [{Os3(CO)10(μ-η2-CH= CHPh)}2(μ4-Hg)]

Yat Kun Au; Wing Tak Wong

doi:10.1039/DT9950001389

Dalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)₄{(μ- Hg)Os₃(CO)₁₀(μ-η²-CH=CHPh)} ₂] and [{Os₃(CO)₁₀(μ-η²-CH= CHPh)}₂(μ₄-Hg)]

Yat Kun Au
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

6 Citations (Scopus)

Abstract

Reaction of [Os3H2(CO)10] with Hg(C≡CPh)2 afforded the novel mixed-metal clusters cis-[Os(CO)4{(μ-Hg)Os3(CO)10(μ- η2-CH=CHPh)}2] 1 and [{Os3(CO) 10(μ-η2-CH=CHPh)}2(μ4-Hg)] 2 in moderate yield, the crystal structures of which have been determined; 1 converts into 2 via Hg-Os bond cleavage under ambient conditions.

Original language	English
Pages (from-to)	1389-1390
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	8
DOIs	https://doi.org/10.1039/DT9950001389
Publication status	Published - 1 Dec 1995
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

More information

10.1039/DT9950001389

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@article{a78b9ad3a22a49bf96d12d15e7f6b607,

title = "Dalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)4\{(μ- Hg)Os3(CO)10(μ-η2-CH=CHPh)\} 2] and [\{Os3(CO)10(μ-η2-CH= CHPh)\}2(μ4-Hg)]",

abstract = "Reaction of [Os3H2(CO)10] with Hg(C≡CPh)2 afforded the novel mixed-metal clusters cis-[Os(CO)4\{(μ-Hg)Os3(CO)10(μ- η2-CH=CHPh)\}2] 1 and [\{Os3(CO) 10(μ-η2-CH=CHPh)\}2(μ4-Hg)] 2 in moderate yield, the crystal structures of which have been determined; 1 converts into 2 via Hg-Os bond cleavage under ambient conditions.",

author = "Au, \{Yat Kun\} and Wong, \{Wing Tak\}",

year = "1995",

month = dec,

day = "1",

doi = "10.1039/DT9950001389",

language = "English",

pages = "1389--1390",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "8",

}

Dalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)₄{(μ- Hg)Os₃(CO)₁₀(μ-η²-CH=CHPh)} ₂] and [{Os₃(CO)₁₀(μ-η²-CH= CHPh)}₂(μ₄-Hg)]. / Au, Yat Kun; Wong, Wing Tak.
In: Journal of the Chemical Society, Dalton Transactions, No. 8, 01.12.1995, p. 1389-1390.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Dalton communications. Synthesis of novel mixed-metal clusters of mercury and osmium; crystal and molecular structures of cis-[Os(CO)4{(μ- Hg)Os3(CO)10(μ-η2-CH=CHPh)} 2] and [{Os3(CO)10(μ-η2-CH= CHPh)}2(μ4-Hg)]

AU - Au, Yat Kun

AU - Wong, Wing Tak

PY - 1995/12/1

Y1 - 1995/12/1

N2 - Reaction of [Os3H2(CO)10] with Hg(C≡CPh)2 afforded the novel mixed-metal clusters cis-[Os(CO)4{(μ-Hg)Os3(CO)10(μ- η2-CH=CHPh)}2] 1 and [{Os3(CO) 10(μ-η2-CH=CHPh)}2(μ4-Hg)] 2 in moderate yield, the crystal structures of which have been determined; 1 converts into 2 via Hg-Os bond cleavage under ambient conditions.

AB - Reaction of [Os3H2(CO)10] with Hg(C≡CPh)2 afforded the novel mixed-metal clusters cis-[Os(CO)4{(μ-Hg)Os3(CO)10(μ- η2-CH=CHPh)}2] 1 and [{Os3(CO) 10(μ-η2-CH=CHPh)}2(μ4-Hg)] 2 in moderate yield, the crystal structures of which have been determined; 1 converts into 2 via Hg-Os bond cleavage under ambient conditions.

UR - https://www.scopus.com/pages/publications/37049082622

U2 - 10.1039/DT9950001389

DO - 10.1039/DT9950001389

M3 - Journal article

SN - 1472-7773

SP - 1389

EP - 1390

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 8

ER -