Abstract
Reaction of [Os3H2(CO)10] with Hg(C≡CPh)2 afforded the novel mixed-metal clusters cis-[Os(CO)4{(μ-Hg)Os3(CO)10(μ- η2-CH=CHPh)}2] 1 and [{Os3(CO) 10(μ-η2-CH=CHPh)}2(μ4-Hg)] 2 in moderate yield, the crystal structures of which have been determined; 1 converts into 2 via Hg-Os bond cleavage under ambient conditions.
Original language | English |
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Pages (from-to) | 1389-1390 |
Number of pages | 2 |
Journal | Journal of the Chemical Society, Dalton Transactions |
Issue number | 8 |
DOIs | |
Publication status | Published - 1 Dec 1995 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry