Dalton communications. Synthesis and crystal structure of [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}]

Wai Kwok Wong, Tao Jiang, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

7 Citations (Scopus)

Abstract

The interaction of (Ph2P)NC(Ph)[N(SiMe3)2] with 1 equivalent of [RuCl2(PPh3)3] in tetrahydrofuran gave [RuCl2(PPh3){N(SiMe3)C(Ph)NH(PPh2)}] whose structure established by X-ray crystallography suggests the presence of a γ-agostic interaction between ruthenium and one of the methyl groups of the N(SiMe3) imino group.
Original languageEnglish
Pages (from-to)3087-3088
Number of pages2
JournalJournal of the Chemical Society, Dalton Transactions
Issue number18
DOIs
Publication statusPublished - 1 Dec 1995
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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