Covalently linked anthracene-containing supramolecular complexes of triosmium carbonyl clusters: Synthesis, crystal structures and solvatochromic behaviour

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Abstract

Three novel anthracene-containing supramolecules [Os3(μ-H)2(CO)9(μ3-CNC5H4CHCHC14H9)] 1, [Os3(μ-H)2(CO)9(μ3-CNC5H4CH2CH2C14H9)] 2 and [Os3(μ-H)(CO)10(μ-NC5H3CHCHC14H9)] 3 (C14H10= anthracene) have been synthesised and the crystal structures of 2 and 3 determined; UV/VIS spectroscopic studies indicated a significant metal-anthracene interaction in the ground state via the conjugated ligand group in 1.
Original languageEnglish
Pages (from-to)1853-1856
Number of pages4
JournalJournal of the Chemical Society - Dalton Transactions
Issue number9
DOIs
Publication statusPublished - 7 May 1996
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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