Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts

Gang Wang; Biquan Xiong; Congshan Zhou; Yu Liu; Weifeng Xu; Chang An Yang; Ke Wen Tang; Wai Yeung Wong

doi:10.1002/asia.201901284

Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts

Gang Wang, Biquan Xiong, Congshan Zhou, Yu Liu, Weifeng Xu, Chang An Yang, Ke Wen Tang, Wai Yeung Wong (Corresponding Author)

Research output: Journal article publication › Journal article › Academic research › peer-review

4 Citations (Scopus)

Abstract

A copper-catalyzed diphenylation of P(O)−OH bonds with cyclic diaryliodonium salts is described. Valuable 2′-iodo substituted biaryl phosphinic/phosphoric acid esters were obtained in good to excellent yields, which could be further transformed to diversified building blocks for the synthesis of bioactive compounds, pharmaceuticals and functional materials.

Original language	English
Pages (from-to)	4365-4374
Number of pages	10
Journal	Chemistry - An Asian Journal
Volume	14
Issue number	23
DOIs	https://doi.org/10.1002/asia.201901284
Publication status	Published - 2 Dec 2019

Keywords

copper catalysis
cyclic diaryliodonium salts
diphenylation
P(O)−OH bonds

ASJC Scopus subject areas

Biochemistry
Organic Chemistry

More information

10.1002/asia.201901284

Cite this

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title = "Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts",

abstract = "A copper-catalyzed diphenylation of P(O)−OH bonds with cyclic diaryliodonium salts is described. Valuable 2′-iodo substituted biaryl phosphinic/phosphoric acid esters were obtained in good to excellent yields, which could be further transformed to diversified building blocks for the synthesis of bioactive compounds, pharmaceuticals and functional materials.",

keywords = "copper catalysis, cyclic diaryliodonium salts, diphenylation, P(O)−OH bonds",

author = "Gang Wang and Biquan Xiong and Congshan Zhou and Yu Liu and Weifeng Xu and Yang, {Chang An} and Tang, {Ke Wen} and Wong, {Wai Yeung}",

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doi = "10.1002/asia.201901284",

language = "English",

volume = "14",

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journal = "Chemistry - An Asian Journal",

issn = "1861-4728",

publisher = "John Wiley and Sons Ltd",

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Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts. / Wang, Gang; Xiong, Biquan; Zhou, Congshan; Liu, Yu; Xu, Weifeng; Yang, Chang An; Tang, Ke Wen; Wong, Wai Yeung (Corresponding Author).

In: Chemistry - An Asian Journal, Vol. 14, No. 23, 02.12.2019, p. 4365-4374.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts

AU - Wang, Gang

AU - Xiong, Biquan

AU - Zhou, Congshan

AU - Liu, Yu

AU - Xu, Weifeng

AU - Yang, Chang An

AU - Tang, Ke Wen

AU - Wong, Wai Yeung

PY - 2019/12/2

Y1 - 2019/12/2

N2 - A copper-catalyzed diphenylation of P(O)−OH bonds with cyclic diaryliodonium salts is described. Valuable 2′-iodo substituted biaryl phosphinic/phosphoric acid esters were obtained in good to excellent yields, which could be further transformed to diversified building blocks for the synthesis of bioactive compounds, pharmaceuticals and functional materials.

AB - A copper-catalyzed diphenylation of P(O)−OH bonds with cyclic diaryliodonium salts is described. Valuable 2′-iodo substituted biaryl phosphinic/phosphoric acid esters were obtained in good to excellent yields, which could be further transformed to diversified building blocks for the synthesis of bioactive compounds, pharmaceuticals and functional materials.

KW - copper catalysis

KW - cyclic diaryliodonium salts

KW - diphenylation

KW - P(O)−OH bonds

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U2 - 10.1002/asia.201901284

DO - 10.1002/asia.201901284

M3 - Journal article

C2 - 31646736

AN - SCOPUS:85075528456

VL - 14

SP - 4365

EP - 4374

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

SN - 1861-4728

IS - 23

ER -

Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts

Abstract

Keywords

ASJC Scopus subject areas

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