Copper-Catalyzed Diphenylation of P(O)-OH Bonds with Cyclic Diaryliodonium Salts

Gang Wang, Biquan Xiong, Congshan Zhou, Yu Liu, Weifeng Xu, Chang An Yang, Ke Wen Tang, Wai Yeung Wong (Corresponding Author)

Research output: Journal article publicationJournal articleAcademic researchpeer-review

4 Citations (Scopus)

Abstract

A copper-catalyzed diphenylation of P(O)−OH bonds with cyclic diaryliodonium salts is described. Valuable 2′-iodo substituted biaryl phosphinic/phosphoric acid esters were obtained in good to excellent yields, which could be further transformed to diversified building blocks for the synthesis of bioactive compounds, pharmaceuticals and functional materials.

Original languageEnglish
Pages (from-to)4365-4374
Number of pages10
JournalChemistry - An Asian Journal
Volume14
Issue number23
DOIs
Publication statusPublished - 2 Dec 2019

Keywords

  • copper catalysis
  • cyclic diaryliodonium salts
  • diphenylation
  • P(O)−OH bonds

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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