Constructing Z-scheme SnO2/N-doped carbon quantum dots/ZnSn(OH)6 nanohybrids with high redox ability for NO: X removal under VIS-NIR light

Yanfeng Lu, Yu Huang, Jun Ji Cao, Haiwei Li, Wingkei Ho, Shun Cheng Lee

Research output: Journal article publicationJournal articleAcademic researchpeer-review

23 Citations (Scopus)

Abstract

Photocatalysts with a wide optical response range and high oxidation ability are essential for their application in air pollution control. In this study, mesoporous SnO2/NCDs/ZnSn(OH)6 (NCDs = N-doped carbon quantum dots) Z-scheme nanohybrids were synthesized for the first time using an in situ strategy. The ternary Z-scheme catalysts showed significantly enhanced visible and near-infrared light-driven photocatalytic activities for nitric oxide (NO) removal (37%), while the toxic nitrogen dioxide (NO2) intermediate was suppressed completely. The Z-schematic transfer mechanism was confirmed through characterizing the intrinsic properties of the as-prepared sample. The NCDs, as an electron transport bridge, improve both the broad-spectrum light-harvesting ability and the rapid separation of photoinduced electrons. Compared with the binary counterparts, the SnO2/NCDs/ZnSn(OH)6 ternary nanohybrid can generate more reactive oxygen-containing radicals during the photocatalytic reaction, owing to its ability to supply sufficient free surface OH. This study provides insights into the heterogeneous photocatalytic Z-scheme reaction mechanism.

Original languageEnglish
Pages (from-to)15782-15793
Number of pages12
JournalJournal of Materials Chemistry A
Volume7
Issue number26
DOIs
Publication statusPublished - 14 Jul 2019

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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