Cocatalyst-free Photocatalytic Hydrogen Evolution with Simple Heteroleptic Iridium(III) Complexes

Govardhana Babu Bodedla, Daniel Nnaemaka Tritton, Xi Chen, Jianzhang Zhao, Zeling Guo, Ken Cham Fai Leung, Wai Yeung Wong (Corresponding Author), Xunjin Zhu

Research output: Journal article publicationJournal articleAcademic researchpeer-review

4 Citations (Scopus)

Abstract

A simple heteroleptic iridium(III) photosensitizer, Ir-1, containing two ligands 5-(trifluoromethyl)-2-phenylpyridine (CN-CF3) and bipyridine (NN) has for the first time been studied for cocatalyst-free photocatalytic hydrogen evolution (PHE). The complex Ir-1 produces a hydrogen production rate (ηH2) of 3.2 mmol g-1 h-1, which is over 3.6-fold higher than that of the control complex Ir-2 (0.9 mmol g-1 h-1) containing bipyridine and 2-phenylpyridine ligands without CF3 groups. The higher ηH2 of Ir-1 could be ascribed to the high light-harvesting property, longer triplet electron lifetime, and more appropriate driving force for accepting electrons from the sacrificial donor, which enable efficient charge separation and transfer of electrons for hydrogen evolution. Additionally, the photostability issues of Ir-1 and Ir-2 are addressed by the selection of suitable organic solvent/water photocatalytic systems.

Original languageEnglish
Pages (from-to)3945-3951
Number of pages7
JournalACS Applied Energy Materials
Volume4
Issue number4
DOIs
Publication statusPublished - 26 Apr 2021

Keywords

  • cocatalyst-free
  • iridium(III) complex
  • photocatalytic hydrogen evolution
  • photostability and reductive quenching

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Energy Engineering and Power Technology
  • Electrochemistry
  • Electrical and Electronic Engineering
  • Materials Chemistry

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