Cobalt-catalyzed oxidation of ethers using oxygen

Pei Li, Howard Alper

Research output: Journal article publicationJournal articleAcademic researchpeer-review

37 Citations (Scopus)

Abstract

Cobalt(II) chloride-catalyzed oxidation of cyclic ethers with oxygen in 1,2-dimethoxyethane gives the corresponding lactones in reasonable to excellent yields. Oxidation of acyclic alkyl benzyl ethers affords the corresponding esters in yields which are dependent on the stability of alkyl radicals. The more stable the alkyl radical, the lower the yield of the formed ester. Oxidation of acyclic alkyl and heterocyclic ethers is also described. A free-radical mechanism is proposed involving participation of superoxocobalt.
Original languageEnglish
Pages (from-to)143-152
Number of pages10
JournalJournal of Molecular Catalysis
Volume72
Issue number2
DOIs
Publication statusPublished - 1 Mar 1992
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)

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