Cobalt-catalyzed carbonylation of benzyl halides using polyethylene glycols as phase-transfer catalysts

Claudia Zucchi; Gyula Pályi; Vilmos Galamb; Ella Sámpár-Szerencsés; László Markó; Pei Li; Howard Alper

doi:10.1021/om950575i

Cobalt-catalyzed carbonylation of benzyl halides using polyethylene glycols as phase-transfer catalysts

Claudia Zucchi
, Gyula Pályi
, Vilmos Galamb
, Ella Sámpár-Szerencsés
, László Markó
, Pei Li
, Howard Alper

Research output: Journal article publication › Journal article › Academic research › peer-review

44 Citations (Scopus)

Abstract

Hydroxycarbonylation of benzyl and substituted benzyl chloride and bromide derivatives was achieved in good yields (up to 97.6%) and quantitative chemoselectivity, in the presence of Co2(CO)8as the transition metal and polyethylene glycols as the phase-transfer catalyst in an organic solvent/20% aqueous NaOH two-phase system under mild conditions (1 bar CO, room temperature). η1-Benzyl-, η3-benzyl-, and (η1-phenylacetyl)cobalt carbonyls were investigated as intermediates of this catalytic process.

Original language	English
Pages (from-to)	3222-3231
Number of pages	10
Journal	Organometallics
Volume	15
Issue number	14
DOIs	https://doi.org/10.1021/om950575i
Publication status	Published - 9 Jul 1996
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om950575i

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title = "Cobalt-catalyzed carbonylation of benzyl halides using polyethylene glycols as phase-transfer catalysts",

abstract = "Hydroxycarbonylation of benzyl and substituted benzyl chloride and bromide derivatives was achieved in good yields (up to 97.6\%) and quantitative chemoselectivity, in the presence of Co2(CO)8as the transition metal and polyethylene glycols as the phase-transfer catalyst in an organic solvent/20\% aqueous NaOH two-phase system under mild conditions (1 bar CO, room temperature). η1-Benzyl-, η3-benzyl-, and (η1-phenylacetyl)cobalt carbonyls were investigated as intermediates of this catalytic process.",

author = "Claudia Zucchi and Gyula P{\'a}lyi and Vilmos Galamb and Ella S{\'a}mp{\'a}r-Szerencs{\'e}s and L{\'a}szl{\'o} Mark{\'o} and Pei Li and Howard Alper",

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TY - JOUR

T1 - Cobalt-catalyzed carbonylation of benzyl halides using polyethylene glycols as phase-transfer catalysts

AU - Zucchi, Claudia

AU - Pályi, Gyula

AU - Galamb, Vilmos

AU - Sámpár-Szerencsés, Ella

AU - Markó, László

AU - Li, Pei

AU - Alper, Howard

PY - 1996/7/9

Y1 - 1996/7/9

N2 - Hydroxycarbonylation of benzyl and substituted benzyl chloride and bromide derivatives was achieved in good yields (up to 97.6%) and quantitative chemoselectivity, in the presence of Co2(CO)8as the transition metal and polyethylene glycols as the phase-transfer catalyst in an organic solvent/20% aqueous NaOH two-phase system under mild conditions (1 bar CO, room temperature). η1-Benzyl-, η3-benzyl-, and (η1-phenylacetyl)cobalt carbonyls were investigated as intermediates of this catalytic process.

AB - Hydroxycarbonylation of benzyl and substituted benzyl chloride and bromide derivatives was achieved in good yields (up to 97.6%) and quantitative chemoselectivity, in the presence of Co2(CO)8as the transition metal and polyethylene glycols as the phase-transfer catalyst in an organic solvent/20% aqueous NaOH two-phase system under mild conditions (1 bar CO, room temperature). η1-Benzyl-, η3-benzyl-, and (η1-phenylacetyl)cobalt carbonyls were investigated as intermediates of this catalytic process.

UR - https://www.scopus.com/pages/publications/0001685051

U2 - 10.1021/om950575i

DO - 10.1021/om950575i

M3 - Journal article

SN - 0276-7333

VL - 15

SP - 3222

EP - 3231

JO - Organometallics

JF - Organometallics

IS - 14

ER -

Cobalt-catalyzed carbonylation of benzyl halides using polyethylene glycols as phase-transfer catalysts

Abstract

ASJC Scopus subject areas

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