Coal pretreatment and Ag-infiltrated anode for high-performance hybrid direct coal fuel cell

Heping Xie, Shuo Zhai, Bin Chen, Tao Liu, Yuan Zhang, Meng Ni, Zongping Shao

Research output: Journal article publicationJournal articleAcademic researchpeer-review

9 Citations (Scopus)

Abstract

Hybrid direct coal fuel cells (HDCFCs) have the potential to convert coal into electrical power in a clean and efficient manner. However, the related coal pretreatment method and the anode activity should both be improved, before the HDCFCs could match the performance of other direct coal fuel cells such as those based on solid oxide. In this study, we pyrolysed bituminous coal at 800 °C followed by modification with acetic acid, in order to remove organic volatiles and reintroduce surface functional groups, respectively. The result was a modified char that was highly pure and with high oxidation activity. Further, the Ni-(Y2O3)0.08(ZrO2)0.92 anode was infiltrated with Ag nanoparticles as an effective catalyst to promote the electro-oxidation of carbon. Under optimised conditions, the HDCFC with Ag-infiltrated anode and modified char as fuel demonstrated a maximum power density (403 mW cm−2 at 750 °C) that exceeds previous results for coal-based fuels. The cell also showed stable operation for 14 h, with a fuel conversion of 97.22% and Faradic efficiency of 61.06% using 0.4 g modified char.

Original languageEnglish
Article number114197
JournalApplied Energy
Volume260
DOIs
Publication statusPublished - 15 Feb 2020

Keywords

  • Coal pretreatment
  • Direct carbon fuel cell
  • Faradic efficiency
  • High fuel conversion
  • Nanosized Ag infiltration

ASJC Scopus subject areas

  • Building and Construction
  • Energy(all)
  • Mechanical Engineering
  • Management, Monitoring, Policy and Law

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