Co-ordination of a macrocyclic quadridentate tertiary amine ligand in the cis configuration: X-ray crystal structure of cis-[RuLCl2]ClO4(L = 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane)

Chi Ming Che; Wai Tong Tang; Wing Tak Wong; Hon Wah Lam; Ting Fong Lai

doi:10.1039/DT9900002077

Co-ordination of a macrocyclic quadridentate tertiary amine ligand in the cis configuration: X-ray crystal structure of cis-[RuLCl₂]ClO₄(L = 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane)

Chi Ming Che, Wai Tong Tang, Wing Tak Wong, Hon Wah Lam, Ting Fong Lai

Research output: Journal article publication › Journal article › Academic research › peer-review

4 Citations (Scopus)

Abstract

Reaction of K2[RuCl5(H2O)] with 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane(L) in ethanol yielded cis-[RuLCl2]ClO4. The optical spectrum shows an intense pπ(Cl) → dπ(Ru) charge-transfer transition at 378 nm. The cis-[RuLCl2]+cation [space group P21/n, a = 12.388(2), b = 12.740(2), c = 12.853(4) Å, β = 96.68(2)°, Z = 4; R = 0.048 for 1 897 observed Mo-Kαdata] is distorted octahedral with two Ru-Cl bonds cis to each other. The measured Ru-Cl distances [2.406(3) and 2.370(4) Å] are unusually long for a ruthenium(III) system.

Original language	English
Pages (from-to)	2077-2079
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	7
DOIs	https://doi.org/10.1039/DT9900002077
Publication status	Published - 1 Dec 1990
Externally published	Yes

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General Chemistry

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10.1039/DT9900002077

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Che, C. M., Tang, W. T., Wong, W. T., Lam, H. W., & Lai, T. F. (1990). Co-ordination of a macrocyclic quadridentate tertiary amine ligand in the cis configuration: X-ray crystal structure of cis-[RuLCl₂]ClO₄(L = 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane). Journal of the Chemical Society, Dalton Transactions, (7), 2077-2079. https://doi.org/10.1039/DT9900002077

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title = "Co-ordination of a macrocyclic quadridentate tertiary amine ligand in the cis configuration: X-ray crystal structure of cis-[RuLCl2]ClO4(L = 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane)",

abstract = "Reaction of K2[RuCl5(H2O)] with 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane(L) in ethanol yielded cis-[RuLCl2]ClO4. The optical spectrum shows an intense pπ(Cl) → dπ(Ru) charge-transfer transition at 378 nm. The cis-[RuLCl2]+cation [space group P21/n, a = 12.388(2), b = 12.740(2), c = 12.853(4) {\AA}, β = 96.68(2)°, Z = 4; R = 0.048 for 1 897 observed Mo-Kαdata] is distorted octahedral with two Ru-Cl bonds cis to each other. The measured Ru-Cl distances [2.406(3) and 2.370(4) {\AA}] are unusually long for a ruthenium(III) system.",

author = "Che, {Chi Ming} and Tang, {Wai Tong} and Wong, {Wing Tak} and Lam, {Hon Wah} and Lai, {Ting Fong}",

year = "1990",

month = dec,

day = "1",

doi = "10.1039/DT9900002077",

language = "English",

pages = "2077--2079",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

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}

Co-ordination of a macrocyclic quadridentate tertiary amine ligand in the cis configuration: X-ray crystal structure of cis-[RuLCl₂]ClO₄(L = 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane). / Che, Chi Ming; Tang, Wai Tong; Wong, Wing Tak et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 7, 01.12.1990, p. 2077-2079.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Co-ordination of a macrocyclic quadridentate tertiary amine ligand in the cis configuration: X-ray crystal structure of cis-[RuLCl2]ClO4(L = 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane)

AU - Che, Chi Ming

AU - Tang, Wai Tong

AU - Wong, Wing Tak

AU - Lam, Hon Wah

AU - Lai, Ting Fong

PY - 1990/12/1

Y1 - 1990/12/1

N2 - Reaction of K2[RuCl5(H2O)] with 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane(L) in ethanol yielded cis-[RuLCl2]ClO4. The optical spectrum shows an intense pπ(Cl) → dπ(Ru) charge-transfer transition at 378 nm. The cis-[RuLCl2]+cation [space group P21/n, a = 12.388(2), b = 12.740(2), c = 12.853(4) Å, β = 96.68(2)°, Z = 4; R = 0.048 for 1 897 observed Mo-Kαdata] is distorted octahedral with two Ru-Cl bonds cis to each other. The measured Ru-Cl distances [2.406(3) and 2.370(4) Å] are unusually long for a ruthenium(III) system.

AB - Reaction of K2[RuCl5(H2O)] with 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane(L) in ethanol yielded cis-[RuLCl2]ClO4. The optical spectrum shows an intense pπ(Cl) → dπ(Ru) charge-transfer transition at 378 nm. The cis-[RuLCl2]+cation [space group P21/n, a = 12.388(2), b = 12.740(2), c = 12.853(4) Å, β = 96.68(2)°, Z = 4; R = 0.048 for 1 897 observed Mo-Kαdata] is distorted octahedral with two Ru-Cl bonds cis to each other. The measured Ru-Cl distances [2.406(3) and 2.370(4) Å] are unusually long for a ruthenium(III) system.

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U2 - 10.1039/DT9900002077

DO - 10.1039/DT9900002077

M3 - Journal article

SN - 1472-7773

SP - 2077

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JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

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Co-ordination of a macrocyclic quadridentate tertiary amine ligand in the cis configuration: X-ray crystal structure of cis-[RuLCl₂]ClO₄(L = 1,4,7,10-tetramethyl-1,4,7,10-tetra-azacyclotridecane)

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