Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction

Hoi Lun Kwong; Kwok Mei Lau; Wing Sze Lee; Wing Tak Wong

doi:10.1039/a902177i

Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction

Hoi Lun Kwong
, Kwok Mei Lau
, Wing Sze Lee
, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

36 Citations (Scopus)

Abstract

A chiral bipyridine zinc(II) complex, Zn(L)Cl2 (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl2 with AgCF3SO3 gave Zn(L)(CF3SO3)2 in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60%.

Original language	English
Pages (from-to)	629-632
Number of pages	4
Journal	New Journal of Chemistry
Volume	23
Issue number	6
DOIs	https://doi.org/10.1039/a902177i
Publication status	Published - 1 Jan 1999

ASJC Scopus subject areas

Catalysis
General Chemistry
Materials Chemistry

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10.1039/a902177i

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abstract = "A chiral bipyridine zinc(II) complex, Zn(L)Cl2 (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl2 with AgCF3SO3 gave Zn(L)(CF3SO3)2 in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60\%.",

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AU - Kwong, Hoi Lun

AU - Lau, Kwok Mei

AU - Lee, Wing Sze

AU - Wong, Wing Tak

PY - 1999/1/1

Y1 - 1999/1/1

N2 - A chiral bipyridine zinc(II) complex, Zn(L)Cl2 (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl2 with AgCF3SO3 gave Zn(L)(CF3SO3)2 in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60%.

AB - A chiral bipyridine zinc(II) complex, Zn(L)Cl2 (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl2 with AgCF3SO3 gave Zn(L)(CF3SO3)2 in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60%.

UR - https://www.scopus.com/pages/publications/0032813641

U2 - 10.1039/a902177i

DO - 10.1039/a902177i

M3 - Journal article

SN - 1144-0546

VL - 23

SP - 629

EP - 632

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 6

ER -

Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction

Abstract

ASJC Scopus subject areas

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