Chiral zinc(II) bipyridine complex. Crystal structure and catalytic activity in asymmetric allylation reaction

Hoi Lun Kwong, Kwok Mei Lau, Wing Sze Lee, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

36 Citations (Scopus)

Abstract

A chiral bipyridine zinc(II) complex, Zn(L)Cl2 (L = chiral bipyridine), has been prepared and characterized by usual spectroscopic means and X-ray crystallography. Reaction of Zn(L)Cl2 with AgCF3SO3 gave Zn(L)(CF3SO3)2 in situ; this complex is an active catalyst for allylation of aldehydes with enantiomeric excesses up to 60%.
Original languageEnglish
Pages (from-to)629-632
Number of pages4
JournalNew Journal of Chemistry
Volume23
Issue number6
DOIs
Publication statusPublished - 1 Jan 1999

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Materials Chemistry

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