Chiral ruthenium(IV)-oxo complexes. Structure, reactivities of [Ru(terpy)(N∩N)O]2+(N∩N = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane) and [Ru(Me3tacn)(cbpy)O]2+(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine)

Wing Chi Cheng; Wing Yiu Yu; Jin Zhu; Kung Kai Cheung; Shie Ming Peng; Chung Kwong Poon; Chi Ming Che

Chiral ruthenium(IV)-oxo complexes. Structure, reactivities of [Ru(terpy)(N∩N)O]²⁺(N∩N = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane) and [Ru(Me₃tacn)(cbpy)O]²⁺(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine)

Wing Chi Cheng, Wing Yiu Yu, Jin Zhu, Kung Kai Cheung, Shie Ming Peng, Chung Kwong Poon, Chi Ming Che

Research output: Journal article publication › Journal article › Academic research › peer-review

Abstract

The complexes [RuIV(terpy)(cxhn)O](ClO4)2(cxhn = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane, terpy = 2,2′:6′,2″(terpyridine) and RuIV(Me3tacn)(cbpy)O](ClO4)2(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine and Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) have been prepared and crystal structures of [RuIV(terpy)(cxhn)O](ClO4)2and [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2have been determined [RuIV(terpy)(cxhn)O](ClO4)2H2O, C25H35Cl2N5O10Ru, Mr= 737.68, space group P21ln, monoclinic, a = 8.215(5), b = 14.650(7), c = 24.261(10) Å, β = 94 78(4)°, Z = 4, [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2, C21H35Cl2N5O9Ru, Mr= 673.52, space group P21ln, monoclinic, a = 8.463(1), b = 10.751(1), c = 30.192(3) Å, β = 91.77(1)°, Z = 4. The Ru=O distance in [RuIV(terpy)(cxhn)O](ClO4)2is 1.827(14) Å. All the ruthenium-oxo complexes react with alkenes to give the corresponding epoxides. Stoichiometric oxidation of styrene and 4-chlorostyrene by [RuIV(terpy)(1R,2R-cxhn)O](ClO4)2gave the corresponding epoxide with no enantiomeric excess. Using [RuIV(Me3tacn)(cbpy)O](ClO4)2, a 9% enantiomeric excess of R-styrene oxide and R-4-chlorostyrene oxide were found in the oxidation of both styrene and 4-chlorostyrene, respectively.

Original language	English
Pages (from-to)	105-113
Number of pages	9
Journal	Inorganica Chimica Acta
Volume	242
Issue number	1-2
Publication status	Published - 15 Feb 1996
Externally published	Yes

Keywords

Chiral amine complexes
Crystal structure
Oxo complexes
Ruthenium complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Cheng, W. C., Yu, W. Y., Zhu, J., Cheung, K. K., Peng, S. M., Poon, C. K., & Che, C. M. (1996). Chiral ruthenium(IV)-oxo complexes. Structure, reactivities of [Ru(terpy)(N∩N)O]²⁺(N∩N = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane) and [Ru(Me₃tacn)(cbpy)O]²⁺(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine). Inorganica Chimica Acta, 242(1-2), 105-113.

@article{7313dd42106f4b889b1b170172d73dd7,

title = "Chiral ruthenium(IV)-oxo complexes. Structure, reactivities of [Ru(terpy)(N∩N)O]2+(N∩N = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane) and [Ru(Me3tacn)(cbpy)O]2+(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine)",

abstract = "The complexes [RuIV(terpy)(cxhn)O](ClO4)2(cxhn = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane, terpy = 2,2′:6′,2″(terpyridine) and RuIV(Me3tacn)(cbpy)O](ClO4)2(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine and Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) have been prepared and crystal structures of [RuIV(terpy)(cxhn)O](ClO4)2and [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2have been determined [RuIV(terpy)(cxhn)O](ClO4)2H2O, C25H35Cl2N5O10Ru, Mr= 737.68, space group P21ln, monoclinic, a = 8.215(5), b = 14.650(7), c = 24.261(10) {\AA}, β = 94 78(4)°, Z = 4, [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2, C21H35Cl2N5O9Ru, Mr= 673.52, space group P21ln, monoclinic, a = 8.463(1), b = 10.751(1), c = 30.192(3) {\AA}, β = 91.77(1)°, Z = 4. The Ru=O distance in [RuIV(terpy)(cxhn)O](ClO4)2is 1.827(14) {\AA}. All the ruthenium-oxo complexes react with alkenes to give the corresponding epoxides. Stoichiometric oxidation of styrene and 4-chlorostyrene by [RuIV(terpy)(1R,2R-cxhn)O](ClO4)2gave the corresponding epoxide with no enantiomeric excess. Using [RuIV(Me3tacn)(cbpy)O](ClO4)2, a 9% enantiomeric excess of R-styrene oxide and R-4-chlorostyrene oxide were found in the oxidation of both styrene and 4-chlorostyrene, respectively.",

keywords = "Chiral amine complexes, Crystal structure, Oxo complexes, Ruthenium complexes",

author = "Cheng, {Wing Chi} and Yu, {Wing Yiu} and Jin Zhu and Cheung, {Kung Kai} and Peng, {Shie Ming} and Poon, {Chung Kwong} and Che, {Chi Ming}",

year = "1996",

month = feb,

day = "15",

language = "English",

volume = "242",

pages = "105--113",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "1-2",

}

Cheng, WC, Yu, WY, Zhu, J, Cheung, KK, Peng, SM, Poon, CK & Che, CM 1996, 'Chiral ruthenium(IV)-oxo complexes. Structure, reactivities of [Ru(terpy)(N∩N)O]²⁺(N∩N = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane) and [Ru(Me₃tacn)(cbpy)O]²⁺(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine)', Inorganica Chimica Acta, vol. 242, no. 1-2, pp. 105-113.

Chiral ruthenium(IV)-oxo complexes. Structure, reactivities of [Ru(terpy)(N∩N)O]²⁺(N∩N = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane) and [Ru(Me₃tacn)(cbpy)O]²⁺(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine). / Cheng, Wing Chi; Yu, Wing Yiu; Zhu, Jin et al.
In: Inorganica Chimica Acta, Vol. 242, No. 1-2, 15.02.1996, p. 105-113.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Chiral ruthenium(IV)-oxo complexes. Structure, reactivities of [Ru(terpy)(N∩N)O]2+(N∩N = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane) and [Ru(Me3tacn)(cbpy)O]2+(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine)

AU - Cheng, Wing Chi

AU - Yu, Wing Yiu

AU - Zhu, Jin

AU - Cheung, Kung Kai

AU - Peng, Shie Ming

AU - Poon, Chung Kwong

AU - Che, Chi Ming

PY - 1996/2/15

Y1 - 1996/2/15

N2 - The complexes [RuIV(terpy)(cxhn)O](ClO4)2(cxhn = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane, terpy = 2,2′:6′,2″(terpyridine) and RuIV(Me3tacn)(cbpy)O](ClO4)2(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine and Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) have been prepared and crystal structures of [RuIV(terpy)(cxhn)O](ClO4)2and [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2have been determined [RuIV(terpy)(cxhn)O](ClO4)2H2O, C25H35Cl2N5O10Ru, Mr= 737.68, space group P21ln, monoclinic, a = 8.215(5), b = 14.650(7), c = 24.261(10) Å, β = 94 78(4)°, Z = 4, [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2, C21H35Cl2N5O9Ru, Mr= 673.52, space group P21ln, monoclinic, a = 8.463(1), b = 10.751(1), c = 30.192(3) Å, β = 91.77(1)°, Z = 4. The Ru=O distance in [RuIV(terpy)(cxhn)O](ClO4)2is 1.827(14) Å. All the ruthenium-oxo complexes react with alkenes to give the corresponding epoxides. Stoichiometric oxidation of styrene and 4-chlorostyrene by [RuIV(terpy)(1R,2R-cxhn)O](ClO4)2gave the corresponding epoxide with no enantiomeric excess. Using [RuIV(Me3tacn)(cbpy)O](ClO4)2, a 9% enantiomeric excess of R-styrene oxide and R-4-chlorostyrene oxide were found in the oxidation of both styrene and 4-chlorostyrene, respectively.

AB - The complexes [RuIV(terpy)(cxhn)O](ClO4)2(cxhn = N,N,N′,N′-tetramethyl-1,2-diaminocyclohexane, terpy = 2,2′:6′,2″(terpyridine) and RuIV(Me3tacn)(cbpy)O](ClO4)2(cbpy = (-)-3,3′-[(4S-trans)-1,3-dioxolane-4,5-dimethyl]-2,2′-bipyridine and Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) have been prepared and crystal structures of [RuIV(terpy)(cxhn)O](ClO4)2and [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2have been determined [RuIV(terpy)(cxhn)O](ClO4)2H2O, C25H35Cl2N5O10Ru, Mr= 737.68, space group P21ln, monoclinic, a = 8.215(5), b = 14.650(7), c = 24.261(10) Å, β = 94 78(4)°, Z = 4, [RuII(Me3tacn)(3,3′-Me2bpy)(OH2)](ClO4)2, C21H35Cl2N5O9Ru, Mr= 673.52, space group P21ln, monoclinic, a = 8.463(1), b = 10.751(1), c = 30.192(3) Å, β = 91.77(1)°, Z = 4. The Ru=O distance in [RuIV(terpy)(cxhn)O](ClO4)2is 1.827(14) Å. All the ruthenium-oxo complexes react with alkenes to give the corresponding epoxides. Stoichiometric oxidation of styrene and 4-chlorostyrene by [RuIV(terpy)(1R,2R-cxhn)O](ClO4)2gave the corresponding epoxide with no enantiomeric excess. Using [RuIV(Me3tacn)(cbpy)O](ClO4)2, a 9% enantiomeric excess of R-styrene oxide and R-4-chlorostyrene oxide were found in the oxidation of both styrene and 4-chlorostyrene, respectively.

KW - Chiral amine complexes

KW - Crystal structure

KW - Oxo complexes

KW - Ruthenium complexes

UR - http://www.scopus.com/inward/record.url?scp=0000296046&partnerID=8YFLogxK

M3 - Journal article

SN - 0020-1693

VL - 242

SP - 105

EP - 113

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -