Chemically-speciated on-road PM_2.5motor vehicle emission factors in Hong Kong

PM2.5(particle with an aerodynamic diameter less than 2.5 μm) was measured in different microenvironments of Hong Kong (including one urban tunnel, one Hong Kong/Mainland boundary roadside site, two urban roadside sites, and one urban ambient site) in 2003. The concentrations of organic carbon (OC), elemental carbon (EC), water-soluble ions, and up to 40 elements (Na to U) were determined. The average PM2.5mass concentrations were 229±90, 129±95, 69±12, 49±18 μg m-3in the urban tunnel, cross boundary roadside, urban roadside, and urban ambient environments, respectively. Carbonaceous particles (sum of organic material [OM] and EC) were the dominant constituents, on average, accounting for ~82% of PM2.5emissions in the tunnel, ~70% at the three roadside sites, and ~48% at the ambient site, respectively. The OC/EC ratios were 0.6±0.2 and 0.8±0.1 at the tunnel and roadside sites, respectively, suggesting carbonaceous aerosols were mainly from vehicle exhausts. Higher OC/EC ratio (1.9±0.7) occurred at the ambient site, indicating contributions from secondary organic aerosols. The PM2.5emission factor for on-road diesel-fueled vehicles in the urban area of Hong Kong was 257±31 mg veh-1km-1, with a composition of ~51% EC, ~26% OC, and ~9% SO4=. The other inorganic ions and elements made up ~11% of the total PM2.5emissions. OC composed the largest fraction (~51%) in gasoline and liquid petroleum gas (LPG) emissions, followed by EC (~19%). Diesel engines showed higher emission rates than did gasoline and LPG engines for most pollutants, except for V, Br, Sb, and Ba.