Chemical reactivity of [Os3W(μ-H)(CO)14]-anion; synthesis and x-ray crystal structure of [OS3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}]

Janesse Wing Sze Hui; Wing Tak Wong

doi:10.1016/0277-5387(95)00250-V

Chemical reactivity of [Os₃W(μ-H)(CO)¹⁴]^-anion; synthesis and x-ray crystal structure of [OS₃W(μ-H)(CO)₁₂{μ₃-η₃-C(H)C(Ph)C(OH)}]

Janesse Wing Sze Hui, Wing Tak Wong

Research output: Journal article publication › Journal article › Academic research › peer-review

4 Citations (Scopus)

Abstract

The interaction of [Os3W(μ-H)(μ-CO)(CO)13]-anion with phenylacetylene in CHCl3gave [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}] in moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {μ3-η3-C(H)C(Ph)C(OH)} moiety is observed.

Original language	English
Pages (from-to)	541-543
Number of pages	3
Journal	Polyhedron
Volume	15
Issue number	3
DOIs	https://doi.org/10.1016/0277-5387(95)00250-V
Publication status	Published - 1 Jan 1996
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

More information

10.1016/0277-5387(95)00250-V

Cite this

@article{0ab95947ccb44f27b8d5320fc9dd13d7,

title = "Chemical reactivity of [Os3W(μ-H)(CO)14]-anion; synthesis and x-ray crystal structure of [OS3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}]",

abstract = "The interaction of [Os3W(μ-H)(μ-CO)(CO)13]-anion with phenylacetylene in CHCl3gave [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}] in moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {μ3-η3-C(H)C(Ph)C(OH)} moiety is observed.",

author = "Hui, {Janesse Wing Sze} and Wong, {Wing Tak}",

year = "1996",

month = jan,

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doi = "10.1016/0277-5387(95)00250-V",

language = "English",

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journal = "Polyhedron",

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T1 - Chemical reactivity of [Os3W(μ-H)(CO)14]-anion; synthesis and x-ray crystal structure of [OS3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}]

AU - Hui, Janesse Wing Sze

AU - Wong, Wing Tak

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The interaction of [Os3W(μ-H)(μ-CO)(CO)13]-anion with phenylacetylene in CHCl3gave [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}] in moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {μ3-η3-C(H)C(Ph)C(OH)} moiety is observed.

AB - The interaction of [Os3W(μ-H)(μ-CO)(CO)13]-anion with phenylacetylene in CHCl3gave [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}] in moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {μ3-η3-C(H)C(Ph)C(OH)} moiety is observed.

UR - http://www.scopus.com/inward/record.url?scp=0039416066&partnerID=8YFLogxK

U2 - 10.1016/0277-5387(95)00250-V

DO - 10.1016/0277-5387(95)00250-V

M3 - Journal article

VL - 15

SP - 541

EP - 543

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 3