Chemical reactivity of [Os3W(μ-H)(CO)14]-anion; synthesis and x-ray crystal structure of [OS3W(μ-H)(CO)1233-C(H)C(Ph)C(OH)}]

Janesse Wing Sze Hui, Wing Tak Wong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

4 Citations (Scopus)

Abstract

The interaction of [Os3W(μ-H)(μ-CO)(CO)13]-anion with phenylacetylene in CHCl3gave [Os3W(μ-H)(CO)12{μ3-η3-C(H)C(Ph)C(OH)}] in moderate yield. The compound has been fully characterized by both spectroscopic and crystallographic methods. Coupling of a phenylacetylene and a carbonyl ligand to form a cluster bound {μ3-η3-C(H)C(Ph)C(OH)} moiety is observed.
Original languageEnglish
Pages (from-to)541-543
Number of pages3
JournalPolyhedron
Volume15
Issue number3
DOIs
Publication statusPublished - 1 Jan 1996
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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