Characterization of a high-valent ruthenyl (RuIV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2

Chi Ming Che; Kwok Yin Wong; Thomas C.W. Mak

doi:10.1039/C39850000546

Characterization of a high-valent ruthenyl (Ru^IV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[Ru^IV(tmc)O(MeCN)][PF₆]₂

Chi Ming Che, Kwok Yin Wong, Thomas C.W. Mak

Research output: Journal article publication › Journal article › Academic research › peer-review

62 Citations (Scopus)

Abstract

trans-[RuIV(tmc)O(MeCN)][PF6]2(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3with trans-[RuVI(tmc)O2][PF6]2in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) Å.

Original language	English
Pages (from-to)	546-548
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39850000546
Publication status	Published - 1 Jan 1985
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

More information

10.1039/C39850000546

Cite this

Che, C. M., Wong, K. Y., & Mak, T. C. W. (1985). Characterization of a high-valent ruthenyl (Ru^IV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[Ru^IV(tmc)O(MeCN)][PF₆]₂. Journal of the Chemical Society, Chemical Communications, (9), 546-548. https://doi.org/10.1039/C39850000546

@article{e49848dcdbdb4cfa88cc6ef9be562f1e,

title = "Characterization of a high-valent ruthenyl (RuIV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2",

abstract = "trans-[RuIV(tmc)O(MeCN)][PF6]2(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3with trans-[RuVI(tmc)O2][PF6]2in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) {\AA}.",

author = "Che, {Chi Ming} and Wong, {Kwok Yin} and Mak, {Thomas C.W.}",

year = "1985",

month = jan,

day = "1",

doi = "10.1039/C39850000546",

language = "English",

pages = "546--548",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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}

Che, CM, Wong, KY & Mak, TCW 1985, 'Characterization of a high-valent ruthenyl (Ru^IV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[Ru^IV(tmc)O(MeCN)][PF₆]₂', Journal of the Chemical Society, Chemical Communications, no. 9, pp. 546-548. https://doi.org/10.1039/C39850000546

Characterization of a high-valent ruthenyl (Ru^IV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[Ru^IV(tmc)O(MeCN)][PF₆]₂. / Che, Chi Ming; Wong, Kwok Yin; Mak, Thomas C.W.

In: Journal of the Chemical Society, Chemical Communications, No. 9, 01.01.1985, p. 546-548.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Characterization of a high-valent ruthenyl (RuIV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2

AU - Che, Chi Ming

AU - Wong, Kwok Yin

AU - Mak, Thomas C.W.

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N2 - trans-[RuIV(tmc)O(MeCN)][PF6]2(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3with trans-[RuVI(tmc)O2][PF6]2in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) Å.

AB - trans-[RuIV(tmc)O(MeCN)][PF6]2(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3with trans-[RuVI(tmc)O2][PF6]2in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) Å.

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DO - 10.1039/C39850000546

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