TY - JOUR
T1 - Characterization of a high-valent ruthenyl (RuIV=O) cation stabilized by the macrocyclic 1,4,8,11-tetramethyl-1,4,8,11-tetra- azacyclotetradecane (tmc) ligand: Crystal and molecular structure of trans-[RuIV(tmc)O(MeCN)][PF6]2
AU - Che, Chi Ming
AU - Wong, Kwok Yin
AU - Mak, Thomas C.W.
PY - 1985/1/1
Y1 - 1985/1/1
N2 - trans-[RuIV(tmc)O(MeCN)][PF6]2(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3with trans-[RuVI(tmc)O2][PF6]2in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) Å.
AB - trans-[RuIV(tmc)O(MeCN)][PF6]2(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been obtained by the reaction of PPh3with trans-[RuVI(tmc)O2][PF6]2in MeCN; the Ru=O distance in this mono-oxo ruthenium(IV) (ruthenyl) species, as determined by X-ray crystallography, is 1.765(5) Å.
UR - http://www.scopus.com/inward/record.url?scp=1542355668&partnerID=8YFLogxK
U2 - 10.1039/C39850000546
DO - 10.1039/C39850000546
M3 - Journal article
SP - 546
EP - 548
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 9
ER -