Catalytic performances of cross-linking humic acids supported Pd/Ni bimetallic catalyst for heck reaction

Qijie Xu; Lei Zhang; Wen Zhong Shi; Yuanchen Cui

doi:10.2478/v10026-009-0031-0

Catalytic performances of cross-linking humic acids supported Pd/Ni bimetallic catalyst for heck reaction

Qijie Xu, Lei Zhang, Wen Zhong Shi, Yuanchen Cui

Research output: Journal article publication › Journal article › Academic research › peer-review

6 Citations (Scopus)

Abstract

The cross-linking humic acids (CL-HAs), epichlorohydrin as the cross-linking reagent and the supported Pd/Ni bimetallic catalysts (CL-HAs-Pd/Ni) were prepared and characterized by IR, AAS, XPS, TEM. The effects of reaction time, temperature, base, solvent and the amount of catalyst on the properties of the catalyst were studied. These catalysts could catalyze the Heck reaction of aryl halides and substituted aryl halides with acrylic acids or styrene successfully; the yields were all above 95%.

Original language	English
Pages (from-to)	22-26
Number of pages	5
Journal	Polish Journal of Chemical Technology
Volume	11
Issue number	3
DOIs	https://doi.org/10.2478/v10026-009-0031-0
Publication status	Published - 1 Jan 2009
Externally published	Yes

Keywords

Cross-linking humic acid
Epichlorohydrin
Heck reaction
Pd/Ni bimetallic catalyst
Supported catalyst

ASJC Scopus subject areas

Biotechnology
Chemistry(all)
Chemical Engineering(all)

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10.2478/v10026-009-0031-0

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title = "Catalytic performances of cross-linking humic acids supported Pd/Ni bimetallic catalyst for heck reaction",

abstract = "The cross-linking humic acids (CL-HAs), epichlorohydrin as the cross-linking reagent and the supported Pd/Ni bimetallic catalysts (CL-HAs-Pd/Ni) were prepared and characterized by IR, AAS, XPS, TEM. The effects of reaction time, temperature, base, solvent and the amount of catalyst on the properties of the catalyst were studied. These catalysts could catalyze the Heck reaction of aryl halides and substituted aryl halides with acrylic acids or styrene successfully; the yields were all above 95%.",

keywords = "Cross-linking humic acid, Epichlorohydrin, Heck reaction, Pd/Ni bimetallic catalyst, Supported catalyst",

author = "Qijie Xu and Lei Zhang and Shi, {Wen Zhong} and Yuanchen Cui",

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doi = "10.2478/v10026-009-0031-0",

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AU - Xu, Qijie

AU - Zhang, Lei

AU - Shi, Wen Zhong

AU - Cui, Yuanchen

PY - 2009/1/1

Y1 - 2009/1/1

N2 - The cross-linking humic acids (CL-HAs), epichlorohydrin as the cross-linking reagent and the supported Pd/Ni bimetallic catalysts (CL-HAs-Pd/Ni) were prepared and characterized by IR, AAS, XPS, TEM. The effects of reaction time, temperature, base, solvent and the amount of catalyst on the properties of the catalyst were studied. These catalysts could catalyze the Heck reaction of aryl halides and substituted aryl halides with acrylic acids or styrene successfully; the yields were all above 95%.

AB - The cross-linking humic acids (CL-HAs), epichlorohydrin as the cross-linking reagent and the supported Pd/Ni bimetallic catalysts (CL-HAs-Pd/Ni) were prepared and characterized by IR, AAS, XPS, TEM. The effects of reaction time, temperature, base, solvent and the amount of catalyst on the properties of the catalyst were studied. These catalysts could catalyze the Heck reaction of aryl halides and substituted aryl halides with acrylic acids or styrene successfully; the yields were all above 95%.

KW - Cross-linking humic acid

KW - Epichlorohydrin

KW - Heck reaction

KW - Pd/Ni bimetallic catalyst

KW - Supported catalyst

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U2 - 10.2478/v10026-009-0031-0

DO - 10.2478/v10026-009-0031-0

M3 - Journal article

SN - 1509-8117

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SP - 22

EP - 26

JO - Polish Journal of Chemical Technology

JF - Polish Journal of Chemical Technology

IS - 3

ER -

Catalytic performances of cross-linking humic acids supported Pd/Ni bimetallic catalyst for heck reaction

Abstract

Keywords

ASJC Scopus subject areas

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