Catalytic and asymmetric cyclopropanation of alkenes catalysed by rhenium(I) bipyridine and terpyridine tricarbonyl complexes

Chi Tung Yeung, Pang Fei Teng, Ho Lun Yeung, Wing Tak Wong, Hoi Lun Kwong

Research output: Journal article publicationJournal articleAcademic researchpeer-review

20 Citations (Scopus)

Abstract

Re(i) tricarbonyl bipyridine and terpyridine complexes catalyse stereospecific cyclopropanation of alkenes; high selectivity of cyclopropane vs coupling and an ee of 73% and 62% for cis- and trans-cyclopropanes of styrene respectively were achieved with the [Re(L)(CO)3(MeCN)]OTf complex (L = chiral C2-symmetric terpyridine ligand).
Original languageEnglish
Pages (from-to)3859-3864
Number of pages6
JournalOrganic and Biomolecular Chemistry
Volume5
Issue number23
DOIs
Publication statusPublished - 21 Nov 2007
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this