TY - JOUR
T1 - Boosting the lithium-ion storage performance of dense MnCO3microsphere anodes via Sb-substitution and construction of neural-like carbon nanotube networks
AU - Lu, Hao
AU - Fang, Yanwu
AU - Yang, Jike
AU - Yang, Mingtong
AU - Du, Qingchuan
AU - Bai, Ling
AU - Xiao, Kang
AU - Masese, Titus
AU - Yang, Xusheng
AU - Huang, Zhen Dong
AU - Ma, Yanwen
PY - 2018/10/1
Y1 - 2018/10/1
N2 - Abstract: To boost the electrochemical performance of MnCO3(MC) microspheres, binary SbxMn1−xCO3(x = 1/3, 1/2 and 2/3) microspheres, labeled SMC-12, SMC-11 and SMC-21, respectively, were prepared using a solvothermal method. A 3D conductive network of carbon nanotubes (CNT) was also successfully built from the inside to the surface of the SMC-12 microspheres to promote electronic and ionic transportation. As observed, the microspheres of SMC-12 were larger and had a more uniform distribution compared with pure MC, SMC-11 and SMC-21. Profiting from the introduction of neural-like CNTs networks, the electrochemical performance and the utility of the SMC-12 microspheres (approximately 3.5–7 µm in diameter) were remarkably improved. The obtained CNTs@SMC-12 composite anode delivered 1066 and 572 mAh g−1at current densities of 500 and 5000 mAg−1after 200 cycles, respectively, which were much higher than the 737 and 297 mAh g−1of bare SMC-12. Graphical abstract: With the successful construction of a 3D “neural”-like CNTs conductive network for the Sb1/3Mn2/3CO3(SMC-12) microsphere, the rate performance, the cyclic stability, the utility of the large size SMC-12 microspheres are remarkably promoted. [Figure not available: see fulltext.]
AB - Abstract: To boost the electrochemical performance of MnCO3(MC) microspheres, binary SbxMn1−xCO3(x = 1/3, 1/2 and 2/3) microspheres, labeled SMC-12, SMC-11 and SMC-21, respectively, were prepared using a solvothermal method. A 3D conductive network of carbon nanotubes (CNT) was also successfully built from the inside to the surface of the SMC-12 microspheres to promote electronic and ionic transportation. As observed, the microspheres of SMC-12 were larger and had a more uniform distribution compared with pure MC, SMC-11 and SMC-21. Profiting from the introduction of neural-like CNTs networks, the electrochemical performance and the utility of the SMC-12 microspheres (approximately 3.5–7 µm in diameter) were remarkably improved. The obtained CNTs@SMC-12 composite anode delivered 1066 and 572 mAh g−1at current densities of 500 and 5000 mAg−1after 200 cycles, respectively, which were much higher than the 737 and 297 mAh g−1of bare SMC-12. Graphical abstract: With the successful construction of a 3D “neural”-like CNTs conductive network for the Sb1/3Mn2/3CO3(SMC-12) microsphere, the rate performance, the cyclic stability, the utility of the large size SMC-12 microspheres are remarkably promoted. [Figure not available: see fulltext.]
KW - Anode materials
KW - Carbon nanotube
KW - Carbonates microspheres
KW - Lithium ion batteries
UR - http://www.scopus.com/inward/record.url?scp=85048095959&partnerID=8YFLogxK
U2 - 10.1007/s10800-018-1212-4
DO - 10.1007/s10800-018-1212-4
M3 - Journal article
SN - 0021-891X
VL - 48
SP - 1105
EP - 1113
JO - Journal of Applied Electrochemistry
JF - Journal of Applied Electrochemistry
IS - 10
ER -