Abstract
We report preliminary A-band resonance Raman spectra of IC2H4C2F4I in order to investigate bond selective electronic excitation and short-time photodissociation dynamics associated with the C-I bond cleavage. The resonance Raman spectra have most of their intensity in peaks tentatively assigned as fundamentals and only a moderate amount of intensity in overtones and combination bands. The resonance Raman intensity patterns in conjunction with results of other iodoalkanes suggest that the C-I bond cleavage has a multidimensional character which is probably greater for C-I bond cleavage at the CF2-I end of the molecule than at the CH2-I end of the molecule.
Original language | English |
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Pages (from-to) | 685-690 |
Number of pages | 6 |
Journal | Chemical Physics Letters |
Volume | 261 |
Issue number | 6 |
DOIs | |
Publication status | Published - 1 Nov 1996 |
Externally published | Yes |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry