Blue, green and red cathodoluminescence of Y2O3 phosphor films prepared by spray pyrolysis

Jianhua Hao, S. A. Studenikin, Michael Cocivera

Research output: Journal article publicationJournal articleAcademic researchpeer-review

180 Citations (Scopus)

Abstract

Thin films of yttrium oxide doped separately with Eu3+, Tb3+and Tm3+were deposited by spray pyrolysis. The effect of preparation conditions on the structural and cathodoluminescent (CL) properties of the thin films was investigated. Films containing Eu3+, Tb3+and Tm3+emitted red, green and blue colors, respectively. Films of yttrium oxide doped with Tm were evaluated in detail. The blue emission of these films had CIE chromaticity coordinates of x = 0.158 and y = 0.150 with a dominant wavelength of 476 nm and a color purity of 78% compared to CIE Standard Source C. The CL intensity of the films under 5 kV beam excitation and a current density of 5 mA/cm2depended strongly on annealing conditions and thulium doping concentration. For Tm-doped films the maximum luminance was 30.4 cd/m2and there was a linear relationship between the CL intensity and excitation voltage. A luminance of 255 cd/m2was obtained for the Eu-doped film. The dominant wavelength was 604 nm with 100% purity, and x = 0.645 and y = 0.357. The luminance for the Tb-doped film was 72 cd/m2with a dominant wavelength of 547 nm and 77% purity.
Original languageEnglish
Pages (from-to)313-319
Number of pages7
JournalJournal of Luminescence
Volume93
Issue number4
DOIs
Publication statusPublished - 1 Aug 2001
Externally publishedYes

Keywords

  • Cathodoluminescence
  • Rare earth dopant
  • Thin film
  • Yttrium oxide phosphors

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics

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