Binuclear gold(I) complexes with bridging diisocyanides and X-ray structures of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] and [Au2(tmb)(CN)2] (tmb=2,5-diisocyano-2,5-dimethylhexane; dmb=1,8-diisocyano-p-menthane)

Che Chi-Ming; Yip Hon-Kay; Wing Tak Wong; Lai Ting-Fong

doi:10.1016/S0020-1693(00)84962-2

Binuclear gold(I) complexes with bridging diisocyanides and X-ray structures of [Au(^tBuNC)(CN)], [Au₂(dmb)(CN)₂] and [Au₂(tmb)(CN)₂] (tmb=2,5-diisocyano-2,5-dimethylhexane; dmb=1,8-diisocyano-p-menthane)

Che Chi-Ming, Yip Hon-Kay, Wing Tak Wong, Lai Ting-Fong

Research output: Journal article publication › Journal article › Academic research › peer-review

26 Citations (Scopus)

Abstract

The synthesis and X-ray crystal structures of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] (dmb = 1,8-diisocyano-p-menthane) and [Au2(tmb)(CN)2] (tmb=2,5-diisocyano-2,5-dimethylhexane) are described. [Au(tBuNC)(CN)]: space group Pnma, a=13.437(1), b=6.469(1), c=9.823(1) Å, Z=4, R=0.055 for 673 observed Mo Kα data; [Au2(dmb)(CN)2]: space group P21/c, a=7.024(2), b=15.255(2), c=15.565(2) Å, β=101.33(2), Z=4, R=0.050 for 2137 observed Mo Kα data; [Au2(tmb)(CN)2]: space group Pbcn, a=15.629(3), b=9.222(4), c=22.777(3), Z=8, R=0.036 for 1127 Mo Kα data. The intermolecular Au...Au separations are 3.568, 3.49-3.73 and 3.21 Å for crystals of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] and [Au2(tmb)(CN)2], respectively. [Au2(tmb)2]2+and [Au2(dmb)2]2+have also been synthesized by the reaction of Au(I) with the diisocyanide ligand. Their UV-Vis spectra are compared and discussed.

Original language	English
Pages (from-to)	177-183
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	197
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)84962-2
Publication status	Published - 15 Jul 1992
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(00)84962-2

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@article{7c2af70221824207860a6389911d8252,

title = "Binuclear gold(I) complexes with bridging diisocyanides and X-ray structures of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] and [Au2(tmb)(CN)2] (tmb=2,5-diisocyano-2,5-dimethylhexane; dmb=1,8-diisocyano-p-menthane)",

abstract = "The synthesis and X-ray crystal structures of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] (dmb = 1,8-diisocyano-p-menthane) and [Au2(tmb)(CN)2] (tmb=2,5-diisocyano-2,5-dimethylhexane) are described. [Au(tBuNC)(CN)]: space group Pnma, a=13.437(1), b=6.469(1), c=9.823(1) {\AA}, Z=4, R=0.055 for 673 observed Mo Kα data; [Au2(dmb)(CN)2]: space group P21/c, a=7.024(2), b=15.255(2), c=15.565(2) {\AA}, β=101.33(2), Z=4, R=0.050 for 2137 observed Mo Kα data; [Au2(tmb)(CN)2]: space group Pbcn, a=15.629(3), b=9.222(4), c=22.777(3), Z=8, R=0.036 for 1127 Mo Kα data. The intermolecular Au...Au separations are 3.568, 3.49-3.73 and 3.21 {\AA} for crystals of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] and [Au2(tmb)(CN)2], respectively. [Au2(tmb)2]2+and [Au2(dmb)2]2+have also been synthesized by the reaction of Au(I) with the diisocyanide ligand. Their UV-Vis spectra are compared and discussed.",

author = "Che Chi-Ming and Yip Hon-Kay and Wong, {Wing Tak} and Lai Ting-Fong",

year = "1992",

month = jul,

day = "15",

doi = "10.1016/S0020-1693(00)84962-2",

language = "English",

volume = "197",

pages = "177--183",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "2",

}

Binuclear gold(I) complexes with bridging diisocyanides and X-ray structures of [Au(^tBuNC)(CN)], [Au₂(dmb)(CN)₂] and [Au₂(tmb)(CN)₂] (tmb=2,5-diisocyano-2,5-dimethylhexane; dmb=1,8-diisocyano-p-menthane). / Chi-Ming, Che; Hon-Kay, Yip; Wong, Wing Tak et al.
In: Inorganica Chimica Acta, Vol. 197, No. 2, 15.07.1992, p. 177-183.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Binuclear gold(I) complexes with bridging diisocyanides and X-ray structures of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] and [Au2(tmb)(CN)2] (tmb=2,5-diisocyano-2,5-dimethylhexane; dmb=1,8-diisocyano-p-menthane)

AU - Chi-Ming, Che

AU - Hon-Kay, Yip

AU - Wong, Wing Tak

AU - Ting-Fong, Lai

PY - 1992/7/15

Y1 - 1992/7/15

N2 - The synthesis and X-ray crystal structures of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] (dmb = 1,8-diisocyano-p-menthane) and [Au2(tmb)(CN)2] (tmb=2,5-diisocyano-2,5-dimethylhexane) are described. [Au(tBuNC)(CN)]: space group Pnma, a=13.437(1), b=6.469(1), c=9.823(1) Å, Z=4, R=0.055 for 673 observed Mo Kα data; [Au2(dmb)(CN)2]: space group P21/c, a=7.024(2), b=15.255(2), c=15.565(2) Å, β=101.33(2), Z=4, R=0.050 for 2137 observed Mo Kα data; [Au2(tmb)(CN)2]: space group Pbcn, a=15.629(3), b=9.222(4), c=22.777(3), Z=8, R=0.036 for 1127 Mo Kα data. The intermolecular Au...Au separations are 3.568, 3.49-3.73 and 3.21 Å for crystals of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] and [Au2(tmb)(CN)2], respectively. [Au2(tmb)2]2+and [Au2(dmb)2]2+have also been synthesized by the reaction of Au(I) with the diisocyanide ligand. Their UV-Vis spectra are compared and discussed.

AB - The synthesis and X-ray crystal structures of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] (dmb = 1,8-diisocyano-p-menthane) and [Au2(tmb)(CN)2] (tmb=2,5-diisocyano-2,5-dimethylhexane) are described. [Au(tBuNC)(CN)]: space group Pnma, a=13.437(1), b=6.469(1), c=9.823(1) Å, Z=4, R=0.055 for 673 observed Mo Kα data; [Au2(dmb)(CN)2]: space group P21/c, a=7.024(2), b=15.255(2), c=15.565(2) Å, β=101.33(2), Z=4, R=0.050 for 2137 observed Mo Kα data; [Au2(tmb)(CN)2]: space group Pbcn, a=15.629(3), b=9.222(4), c=22.777(3), Z=8, R=0.036 for 1127 Mo Kα data. The intermolecular Au...Au separations are 3.568, 3.49-3.73 and 3.21 Å for crystals of [Au(tBuNC)(CN)], [Au2(dmb)(CN)2] and [Au2(tmb)(CN)2], respectively. [Au2(tmb)2]2+and [Au2(dmb)2]2+have also been synthesized by the reaction of Au(I) with the diisocyanide ligand. Their UV-Vis spectra are compared and discussed.

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U2 - 10.1016/S0020-1693(00)84962-2

DO - 10.1016/S0020-1693(00)84962-2

M3 - Journal article

SN - 0020-1693

VL - 197

SP - 177

EP - 183

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Binuclear gold(I) complexes with bridging diisocyanides and X-ray structures of [Au(^tBuNC)(CN)], [Au₂(dmb)(CN)₂] and [Au₂(tmb)(CN)₂] (tmb=2,5-diisocyano-2,5-dimethylhexane; dmb=1,8-diisocyano-p-menthane)

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