Base stable pyrrolidinium cations for alkaline anion exchange membrane applications

Fenglou Gu; Huilong Dong; Youyong Li; Zhe Sun; Feng Yan

doi:10.1021/ma5015148

Base stable pyrrolidinium cations for alkaline anion exchange membrane applications

Fenglou Gu, Huilong Dong, Youyong Li, Zhe Sun, Feng Yan

Research output: Journal article publication › Journal article › Academic research › peer-review

138 Citations (Scopus)

Abstract

The synthesis and characterization of pyrrolidinium cation based anion exchange membranes (AEMs) are reported. Pyrrolidinium cations with various N-substituents (including methyl, ethyl, butyl, octyl, isopropyl, 2-hydroxylethyl, benzyl, and cyclohexylmethyl groups) were synthesized and investigated with respect to their chemical stability in alkaline media. The influence of substitutions on alkaline stability of pyrrolidinium cations was investigated by quantitative1H nuclear magnetic resonance spectroscopy (NMR) and theoretical approaches. N,N-Ethylmethyl-substituted pyrrolidinium cation ([EMPy]+) exhibited the highest alkaline stability in this study. The synthesized AEMs based on [EMPy]+show promising alkaline stability in strongly basic solution. The study of this work should provide a feasible way for improving the alkaline stability of pyrrolidinium cation based AEMs.

Original language	English
Pages (from-to)	6740-6747
Number of pages	8
Journal	Macromolecules
Volume	47
Issue number	19
DOIs	https://doi.org/10.1021/ma5015148
Publication status	Published - 14 Oct 2014
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma5015148

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title = "Base stable pyrrolidinium cations for alkaline anion exchange membrane applications",

abstract = "The synthesis and characterization of pyrrolidinium cation based anion exchange membranes (AEMs) are reported. Pyrrolidinium cations with various N-substituents (including methyl, ethyl, butyl, octyl, isopropyl, 2-hydroxylethyl, benzyl, and cyclohexylmethyl groups) were synthesized and investigated with respect to their chemical stability in alkaline media. The influence of substitutions on alkaline stability of pyrrolidinium cations was investigated by quantitative1H nuclear magnetic resonance spectroscopy (NMR) and theoretical approaches. N,N-Ethylmethyl-substituted pyrrolidinium cation ([EMPy]+) exhibited the highest alkaline stability in this study. The synthesized AEMs based on [EMPy]+show promising alkaline stability in strongly basic solution. The study of this work should provide a feasible way for improving the alkaline stability of pyrrolidinium cation based AEMs.",

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T1 - Base stable pyrrolidinium cations for alkaline anion exchange membrane applications

AU - Gu, Fenglou

AU - Dong, Huilong

AU - Li, Youyong

AU - Sun, Zhe

AU - Yan, Feng

PY - 2014/10/14

Y1 - 2014/10/14

N2 - The synthesis and characterization of pyrrolidinium cation based anion exchange membranes (AEMs) are reported. Pyrrolidinium cations with various N-substituents (including methyl, ethyl, butyl, octyl, isopropyl, 2-hydroxylethyl, benzyl, and cyclohexylmethyl groups) were synthesized and investigated with respect to their chemical stability in alkaline media. The influence of substitutions on alkaline stability of pyrrolidinium cations was investigated by quantitative1H nuclear magnetic resonance spectroscopy (NMR) and theoretical approaches. N,N-Ethylmethyl-substituted pyrrolidinium cation ([EMPy]+) exhibited the highest alkaline stability in this study. The synthesized AEMs based on [EMPy]+show promising alkaline stability in strongly basic solution. The study of this work should provide a feasible way for improving the alkaline stability of pyrrolidinium cation based AEMs.

AB - The synthesis and characterization of pyrrolidinium cation based anion exchange membranes (AEMs) are reported. Pyrrolidinium cations with various N-substituents (including methyl, ethyl, butyl, octyl, isopropyl, 2-hydroxylethyl, benzyl, and cyclohexylmethyl groups) were synthesized and investigated with respect to their chemical stability in alkaline media. The influence of substitutions on alkaline stability of pyrrolidinium cations was investigated by quantitative1H nuclear magnetic resonance spectroscopy (NMR) and theoretical approaches. N,N-Ethylmethyl-substituted pyrrolidinium cation ([EMPy]+) exhibited the highest alkaline stability in this study. The synthesized AEMs based on [EMPy]+show promising alkaline stability in strongly basic solution. The study of this work should provide a feasible way for improving the alkaline stability of pyrrolidinium cation based AEMs.

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U2 - 10.1021/ma5015148

DO - 10.1021/ma5015148

M3 - Journal article

SN - 0024-9297

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JO - Macromolecules

JF - Macromolecules

IS - 19

ER -

Base stable pyrrolidinium cations for alkaline anion exchange membrane applications

Abstract

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