Au Nanoparticles Decorated TiO2Nanotube Arrays as a Recyclable Sensor for Photoenhanced Electrochemical Detection of Bisphenol A

Liangsheng Hu, Chi Chun Fong, Xuming Zhang, Leo Lai Chan, Paul K.S. Lam, Paul K. Chu, Kwok Yin Wong, Mengsu Yang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

89 Citations (Scopus)


A photorefreshable and photoenhanced electrochemical sensing platform for bisphenol A (BPA) detection based on Au nanoparticles (NPs) decorated carbon doped TiO2nanotube arrays (TiO2/Au NTAs) is described. The TiO2/Au NTAs were prepared by quick annealing of anodized nanotubes in argon, followed by controllable electrodeposition of Au NPs. The decoration of Au NPs not only improved photoelectrochemical behavior but also enhanced electrocatalytic activities of the resulted hybrid NTAs. Meanwhile, the high photocatalytic activity of the NTAs allowed the electrode to be readily renewed without damaging the microstructures and surface states after a short UV treatment. The electrochemical detection of BPA on TiO2/Au NTAs electrode was significantly improved under UV irradiation as the electrode could provide fresh reaction surface continuously and the further increased photocurrent resulting from the improved separation efficiency of the photogenerated electron-hole pairs derived from the consumption of holes by BPA. The results showed that the refreshable TiO2/Au NTAs electrode is a promising sensor for long-term BPA monitoring with the detection limit (S/N = 3) of 6.2 nM and the sensitivity of 2.8 μA·μM-1·cm-2.
Original languageEnglish
Pages (from-to)4430-4438
Number of pages9
JournalEnvironmental Science and Technology
Issue number8
Publication statusPublished - 3 May 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

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