Atmospheric deterioration of Qin brick in an environmental chamber at Emperor Qin's Terracotta Museum, China

T. F. Hu, Shuncheng Lee, J. J. Cao, W. K. Ho, K. F. Ho, J. C. Chow, J. G. Watson, B. Rong, Z. S. An

Research output: Journal article publicationJournal articleAcademic researchpeer-review

18 Citations (Scopus)


Potential mechanisms for the changing appearance of Qin terracotta was evaluated on simulated bricks with, SO2, NH3, O3, and a NH3/O3mixture for total dosages of 2.2-5.4 ppm-years. Changes in the surface composition and appearance were evaluated with scanning electron microscopy/energy dispersive X-ray analysis (SEM-EDX) and X-ray photoelectron spectroscopy (XPS). No observable changes with O3exposure were found. Sulfate as sulfur and ammonium as nitrogen increased by 1.2 at% and 0.8 at% of the surface deposit as determined by XPS. O3did not have a detectable effect by itself, but when combined with NH3, NO3as nitrogen increased by 1.5 at%, indicating a strong oxidation of NH3to nitric acid. The combination of outdoor O3infiltration with indoor NH3, presumably from the visitors, appears to have a greater potential for damage than either pollutant by itself. SEM-EDX mapping of the surface showed sulfur associated with calcium and magnesium compounds after SO2exposure, but not before. More detailed microscopic examination showed this primarily in the form of gypsum, especially near cracks and pits in the surface. Both of these mechanisms are probably among the causes of changes in terracotta appearances since they were unearthed in 1974.
Original languageEnglish
Pages (from-to)2578-2583
Number of pages6
JournalJournal of Archaeological Science
Issue number11
Publication statusPublished - 1 Jan 2009


  • Air pollution
  • Indoor air
  • Material damage
  • Museum
  • Terracotta
  • XPS

ASJC Scopus subject areas

  • Archaeology
  • Archaeology


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