An improved electrochemical model for the NH₃fed proton conducting solid oxide fuel cells at intermediate temperatures

An improved electrochemical model is developed to study the ammonia fed solid oxide fuel cell based on proton conducting electrolyte (SOFC-H). Including the chemical reaction kinetics of NH3catalytic thermal decomposition, the present model can be used to predict the performance of the NH3fed SOFC-H at an intermediate temperature (i.e. 773 K). Comparison between the simulation results using the present model and experimental data from literature validates the accuracy of this model. Parametrical analyses reveal that at a high operating temperature (i.e. 1073 K), the NH3fuel is completely decomposed to H2and N2within a very thin layer (30 μm) near the anode surface of an SOFC-H. It is also found that operating the NH3fed SOFC-H at an intermediate temperature of 773 K is feasible due to sufficiently high rate of NH3decomposition. However, further decreasing the temperature to 673 K is not recommended as less than 10% NH3fuel can be decomposed to H2and N2in the SOFC-H. The effects of current density and electrode microstructure on the performance of the NH3fed SOFC-H are also studied. It is found that increasing electrode porosity and pore size is beneficial to increase the partial pressure of H2at the anode-electrolyte interface. The model developed in this paper can be extended to 2D or 3D models to study practical tubular or planar SOFCs.