TY - JOUR
T1 - All-Solution-Processed Multilayered White Polymer Light-Emitting Diodes (WPLEDs) Based on Cross-Linked [Ir(4-vb-PBI)2(acac)]
AU - Li, Wentao
AU - He, Yani
AU - Miao, Tiezheng
AU - LuÌ, Xingqiang
AU - Fu, Guorui
AU - Wong, Wai Yeung
AU - He, Hongshan
N1 - Publisher Copyright:
© 2021 American Chemical Society. All rights reserved.
PY - 2021/3/10
Y1 - 2021/3/10
N2 - All-solution-processed multilayered white polymer light-emitting diodes (WPLEDs) are promising candidates for low-cost and large-area flexible full-color flat-panel displays and solid-state lighting. However, it is still challenging to improve their performance. In this work, based on an elegant strategy of orthogonal materials, the utilization of the cross-linked Ir3+ polymer film poly(NVK-co-[Ir(4-vb-PBI)2(acac)]-co-NVK) (NVK = N-vinyl-carbazole; 4-vb-HPBI = 1-(4-vinylbenzyl)-2-phenyl-1H-benzo[d]imidazole; and Hacac = acetylacetone) as the emitting layer (EML) between a hydrophilic polymer film poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the hole injection layer (HIL) and a hydrophobic polymer film poly(vinyl-PBD) (vinyl-PBD = 2-(4-(tert-butyl)phenyl)-5-(4′-vinyl-[1,1′-biphenyl]-4-yl)-2,5-dihydro-1,3,4-oxadiazole) as the electron transport layer (ETL) led to the successful fabrication of reliable all-solution-processed multilayered WPLEDs. The device exhibits a ΕCEMax of 18.19 cd/A, a ΕPEMax of 8.16 lm/W, and a ΕEQEMax of 9.32% with stable white light (Commission International De L'Eclairage (CIE) coordinates x = 0.269-0.283, y = 0.317-0.330; corrected color temperatures (CCTs) of 7237-8199 K, and CRIs (color rendering indices) of 63-72) under a wide applied-voltage range. Its high performance, especially with record efficiencies among those of reported all-solution-processed WPLEDs, renders cross-linked Ir3+ polymers a new platform to all-solution-processed multilayered WPLEDs.
AB - All-solution-processed multilayered white polymer light-emitting diodes (WPLEDs) are promising candidates for low-cost and large-area flexible full-color flat-panel displays and solid-state lighting. However, it is still challenging to improve their performance. In this work, based on an elegant strategy of orthogonal materials, the utilization of the cross-linked Ir3+ polymer film poly(NVK-co-[Ir(4-vb-PBI)2(acac)]-co-NVK) (NVK = N-vinyl-carbazole; 4-vb-HPBI = 1-(4-vinylbenzyl)-2-phenyl-1H-benzo[d]imidazole; and Hacac = acetylacetone) as the emitting layer (EML) between a hydrophilic polymer film poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the hole injection layer (HIL) and a hydrophobic polymer film poly(vinyl-PBD) (vinyl-PBD = 2-(4-(tert-butyl)phenyl)-5-(4′-vinyl-[1,1′-biphenyl]-4-yl)-2,5-dihydro-1,3,4-oxadiazole) as the electron transport layer (ETL) led to the successful fabrication of reliable all-solution-processed multilayered WPLEDs. The device exhibits a ΕCEMax of 18.19 cd/A, a ΕPEMax of 8.16 lm/W, and a ΕEQEMax of 9.32% with stable white light (Commission International De L'Eclairage (CIE) coordinates x = 0.269-0.283, y = 0.317-0.330; corrected color temperatures (CCTs) of 7237-8199 K, and CRIs (color rendering indices) of 63-72) under a wide applied-voltage range. Its high performance, especially with record efficiencies among those of reported all-solution-processed WPLEDs, renders cross-linked Ir3+ polymers a new platform to all-solution-processed multilayered WPLEDs.
KW - all-solution processing
KW - cross-linked Ir3+ polymer
KW - divinyl-modified [Ir(CâN)2(OâO)]-heteroleptic Ir(III) complex
KW - multilayer
KW - orthogonal materials
KW - WPLED
UR - http://www.scopus.com/inward/record.url?scp=85102964410&partnerID=8YFLogxK
U2 - 10.1021/acsami.0c16581
DO - 10.1021/acsami.0c16581
M3 - Journal article
C2 - 33645976
AN - SCOPUS:85102964410
SN - 1944-8244
VL - 13
SP - 11096
EP - 11107
JO - ACS Applied Materials and Interfaces
JF - ACS Applied Materials and Interfaces
IS - 9
ER -