Air-stable Ir-(P-Phos) complex for highly enantioselective hydrogenation of quinolines and their immobilization in poly(ethylene glycol) dimethyl ether (DMPEG)

Lijin Xu; Kim Hung Lam; Jianxin Ji; Jing Wu; Qing Hua Fan; Wai Hung Lo; Albert S.C. Chan

doi:10.1039/b416397d

Air-stable Ir-(P-Phos) complex for highly enantioselective hydrogenation of quinolines and their immobilization in poly(ethylene glycol) dimethyl ether (DMPEG)

Lijin Xu, Kim Hung Lam, Jianxin Ji, Jing Wu, Qing Hua Fan, Wai Hung Lo, Albert S.C. Chan

Research output: Journal article publication › Journal article › Academic research › peer-review

167 Citations (Scopus)

Abstract

An air-stable catalyst system Ir-(P-Phos) catalyst was found to be highly effective in the asymmetric hydrogenation of quinoline derivatives. The catalyst immobilized in DMPEG was efficiently recovered and reused eight times, retaining reactivity and enantioselectivity.

Original language	English
Pages (from-to)	1390-1392
Number of pages	3
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/b416397d
Publication status	Published - 21 Mar 2005

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b416397d

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title = "Air-stable Ir-(P-Phos) complex for highly enantioselective hydrogenation of quinolines and their immobilization in poly(ethylene glycol) dimethyl ether (DMPEG)",

abstract = "An air-stable catalyst system Ir-(P-Phos) catalyst was found to be highly effective in the asymmetric hydrogenation of quinoline derivatives. The catalyst immobilized in DMPEG was efficiently recovered and reused eight times, retaining reactivity and enantioselectivity.",

author = "Lijin Xu and Lam, {Kim Hung} and Jianxin Ji and Jing Wu and Fan, {Qing Hua} and Lo, {Wai Hung} and Chan, {Albert S.C.}",

year = "2005",

month = mar,

day = "21",

doi = "10.1039/b416397d",

language = "English",

pages = "1390--1392",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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Air-stable Ir-(P-Phos) complex for highly enantioselective hydrogenation of quinolines and their immobilization in poly(ethylene glycol) dimethyl ether (DMPEG). / Xu, Lijin; Lam, Kim Hung; Ji, Jianxin et al.
In: Chemical Communications, No. 11, 21.03.2005, p. 1390-1392.

Research output: Journal article publication › Journal article › Academic research › peer-review

TY - JOUR

T1 - Air-stable Ir-(P-Phos) complex for highly enantioselective hydrogenation of quinolines and their immobilization in poly(ethylene glycol) dimethyl ether (DMPEG)

AU - Xu, Lijin

AU - Lam, Kim Hung

AU - Ji, Jianxin

AU - Wu, Jing

AU - Fan, Qing Hua

AU - Lo, Wai Hung

AU - Chan, Albert S.C.

PY - 2005/3/21

Y1 - 2005/3/21

N2 - An air-stable catalyst system Ir-(P-Phos) catalyst was found to be highly effective in the asymmetric hydrogenation of quinoline derivatives. The catalyst immobilized in DMPEG was efficiently recovered and reused eight times, retaining reactivity and enantioselectivity.

AB - An air-stable catalyst system Ir-(P-Phos) catalyst was found to be highly effective in the asymmetric hydrogenation of quinoline derivatives. The catalyst immobilized in DMPEG was efficiently recovered and reused eight times, retaining reactivity and enantioselectivity.

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U2 - 10.1039/b416397d

DO - 10.1039/b416397d

M3 - Journal article

C2 - 15756313

SN - 1359-7345

SP - 1390

EP - 1392

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Air-stable Ir-(P-Phos) complex for highly enantioselective hydrogenation of quinolines and their immobilization in poly(ethylene glycol) dimethyl ether (DMPEG)

Abstract

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