A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

Ga Lai Law; Tiffany A. Pham; Jide Xu; Kenneth N. Raymond

doi:10.1002/anie.201106748

A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

Ga Lai Law
, Tiffany A. Pham
, Jide Xu
, Kenneth N. Raymond

Research output: Journal article publication › Journal article › Academic research › peer-review

91 Citations (Scopus)

Abstract

Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.

Original language	English
Pages (from-to)	2371-2374
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	10
DOIs	https://doi.org/10.1002/anie.201106748
Publication status	Published - 5 Mar 2012
Externally published	Yes

Keywords

holmium
lanthanide sensitization
octadentate ligands
Vis/NIR emitters
X-ray diffraction

ASJC Scopus subject areas

Catalysis
General Chemistry

More information

10.1002/anie.201106748

Cite this

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title = "A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields",

abstract = "Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.",

keywords = "holmium, lanthanide sensitization, octadentate ligands, Vis/NIR emitters, X-ray diffraction",

author = "Law, \{Ga Lai\} and Pham, \{Tiffany A.\} and Jide Xu and Raymond, \{Kenneth N.\}",

year = "2012",

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T1 - A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

AU - Law, Ga Lai

AU - Pham, Tiffany A.

AU - Xu, Jide

AU - Raymond, Kenneth N.

PY - 2012/3/5

Y1 - 2012/3/5

N2 - Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.

AB - Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.

KW - holmium

KW - lanthanide sensitization

KW - octadentate ligands

KW - Vis/NIR emitters

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84863299216

U2 - 10.1002/anie.201106748

DO - 10.1002/anie.201106748

M3 - Journal article

C2 - 22271666

SN - 1433-7851

VL - 51

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EP - 2374

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 10

ER -

A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

Abstract

Keywords

ASJC Scopus subject areas

More information

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