A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

Ga Lai Law; Tiffany A. Pham; Jide Xu; Kenneth N. Raymond

doi:10.1002/anie.201106748

A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

Ga Lai Law, Tiffany A. Pham, Jide Xu, Kenneth N. Raymond

Research output: Journal article publication › Journal article › Academic research › peer-review

89 Citations (Scopus)

Abstract

Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.

Original language	English
Pages (from-to)	2371-2374
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	10
DOIs	https://doi.org/10.1002/anie.201106748
Publication status	Published - 5 Mar 2012
Externally published	Yes

Keywords

holmium
lanthanide sensitization
octadentate ligands
Vis/NIR emitters
X-ray diffraction

ASJC Scopus subject areas

Catalysis
General Chemistry

More information

10.1002/anie.201106748

Cite this

@article{d812831436b7483cbfc4e39990ee51b3,

title = "A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields",

abstract = "Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.",

keywords = "holmium, lanthanide sensitization, octadentate ligands, Vis/NIR emitters, X-ray diffraction",

author = "Law, {Ga Lai} and Pham, {Tiffany A.} and Jide Xu and Raymond, {Kenneth N.}",

year = "2012",

month = mar,

day = "5",

doi = "10.1002/anie.201106748",

language = "English",

volume = "51",

pages = "2371--2374",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "10",

}

TY - JOUR

T1 - A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

AU - Law, Ga Lai

AU - Pham, Tiffany A.

AU - Xu, Jide

AU - Raymond, Kenneth N.

PY - 2012/3/5

Y1 - 2012/3/5

N2 - Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.

AB - Eight makes a happy Ho(l)me: The versatile octadentate TIAM ligand forms lanthanide complexes (Ln=Sm, Eu, Tb, Dy, Ho) with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.

KW - holmium

KW - lanthanide sensitization

KW - octadentate ligands

KW - Vis/NIR emitters

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=84863299216&partnerID=8YFLogxK

U2 - 10.1002/anie.201106748

DO - 10.1002/anie.201106748

M3 - Journal article

C2 - 22271666

SN - 1433-7851

VL - 51

SP - 2371

EP - 2374

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 10

ER -

A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields

Abstract

Keywords

ASJC Scopus subject areas

More information

Other files and links

Fingerprint

Cite this