Abstract
An efficient route to engineer vinylarene structures by the PdII-catalyzed oxidative coupling of unactivated allylarenes with classic arenes was developed. The methodology features the use of unactivated allylarenes with no prefunctionalization and classic arenes without installed directing groups. A variety of vinylarenes and their saturated derivatives were obtained. They make a great couple: An efficient route to engineer vinylarene structures by PdII-catalyzed oxidative coupling of unactivated allylarenes with classic arenes is developed. The methodology features the use of unactivated allylarenes with no prefunctionalization and classic arenes without installed directing groups. A variety of vinylarenes and their saturated derivatives are obtained. KGaA, Weinheim.
| Original language | English |
|---|---|
| Pages (from-to) | 1599-1603 |
| Number of pages | 5 |
| Journal | ChemCatChem |
| Volume | 6 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 1 Jan 2014 |
Keywords
- allylic compounds
- arenes
- C-H activation
- oxidative coupling
- palladium
ASJC Scopus subject areas
- Catalysis
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry