A polymer tandem solar cell with 10.6% power conversion efficiency

Jingbi You, Letian Dou, Ken Yoshimura, Takehito Kato, Kenichiro Ohya, Tom Moriarty, Keith Emery, Chun Chao Chen, Jing Gao, Gang Li, Yang Yang

Research output: Journal article publicationJournal articleAcademic researchpeer-review

2545 Citations (Scopus)

Abstract

An effective way to improve polymer solar cell efficiency is to use a tandem structure, as a broader part of the spectrum of solar radiation is used and the thermalization loss of photon energy is minimized. In the past, the lack of high-performance low-bandgap polymers was the major limiting factor for achieving high-performance tandem solar cell. Here we report the development of a high-performance low bandgap polymer (bandgap <1.4 eV), poly[2,7-(5,5-bis-(3,7-dimethyloctyl)-5H-dithieno[3,2-b:2′,3′-d] pyran)-alt-4,7-(5,6-difluoro-2,1,3-benzothia diazole)] with a bandgap of 1.38 eV, high mobility, deep highest occupied molecular orbital. As a result, a single-junction device shows high external quantum efficiency of >60% and spectral response that extends to 900 nm, with a power conversion efficiency of 7.9%. The polymer enables a solution processed tandem solar cell with certified 10.6% power conversion efficiency under standard reporting conditions (25C, 1,000 Wm -2, IEC 60904-3 global), which is the first certified polymer solar cell efficiency over 10%.
Original languageEnglish
Article number1446
JournalNature Communications
Volume4
DOIs
Publication statusPublished - 11 Mar 2013
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

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