A novel polynuclear palladium(II) complex with asymmetric coordination of palladium atoms

Kong Cao; Weiping Su; Maochun Hong; Wenjian Zhang; Wing Tak Wong; Jiaxi Lu

doi:10.1039/a805899g

A novel polynuclear palladium(II) complex with asymmetric coordination of palladium atoms

Kong Cao, Weiping Su, Maochun Hong, Wenjian Zhang, Wing Tak Wong, Jiaxi Lu

Research output: Journal article publication › Journal article › Academic research › peer-review

9 Citations (Scopus)

Abstract

The oxidation of [Pd2(dppm)2Cl2] with selenium in the presence of NaSCH2Ph in DMF gives rise to a novel polynuclear complex [Pd4(μ3-Se)2(μ-SCH2Ph)2(μ-dppm)2Cl2]; a single crystal X-ray diffraction analysis shows that all the palladium atoms in the compound are tetra-coordinated with distorted square-planar geometry, of which two are asymmetrically coordinated with selenium, sulfur, chlorine, and phosphorus atoms.

Original language	English
Pages (from-to)	2083-2084
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/a805899g
Publication status	Published - 7 Oct 1998
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a805899g

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abstract = "The oxidation of [Pd2(dppm)2Cl2] with selenium in the presence of NaSCH2Ph in DMF gives rise to a novel polynuclear complex [Pd4(μ3-Se)2(μ-SCH2Ph)2(μ-dppm)2Cl2]; a single crystal X-ray diffraction analysis shows that all the palladium atoms in the compound are tetra-coordinated with distorted square-planar geometry, of which two are asymmetrically coordinated with selenium, sulfur, chlorine, and phosphorus atoms.",

author = "Kong Cao and Weiping Su and Maochun Hong and Wenjian Zhang and Wong, {Wing Tak} and Jiaxi Lu",

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AU - Cao, Kong

AU - Su, Weiping

AU - Hong, Maochun

AU - Zhang, Wenjian

AU - Wong, Wing Tak

AU - Lu, Jiaxi

PY - 1998/10/7

Y1 - 1998/10/7

N2 - The oxidation of [Pd2(dppm)2Cl2] with selenium in the presence of NaSCH2Ph in DMF gives rise to a novel polynuclear complex [Pd4(μ3-Se)2(μ-SCH2Ph)2(μ-dppm)2Cl2]; a single crystal X-ray diffraction analysis shows that all the palladium atoms in the compound are tetra-coordinated with distorted square-planar geometry, of which two are asymmetrically coordinated with selenium, sulfur, chlorine, and phosphorus atoms.

AB - The oxidation of [Pd2(dppm)2Cl2] with selenium in the presence of NaSCH2Ph in DMF gives rise to a novel polynuclear complex [Pd4(μ3-Se)2(μ-SCH2Ph)2(μ-dppm)2Cl2]; a single crystal X-ray diffraction analysis shows that all the palladium atoms in the compound are tetra-coordinated with distorted square-planar geometry, of which two are asymmetrically coordinated with selenium, sulfur, chlorine, and phosphorus atoms.

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U2 - 10.1039/a805899g

DO - 10.1039/a805899g

M3 - Journal article

SN - 1359-7345

SP - 2083

EP - 2084

JO - Chemical Communications

JF - Chemical Communications

IS - 19

ER -

A novel polynuclear palladium(II) complex with asymmetric coordination of palladium atoms

Abstract

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