Abstract
The oxidation of [Pd2(dppm)2Cl2] with selenium in the presence of NaSCH2Ph in DMF gives rise to a novel polynuclear complex [Pd4(μ3-Se)2(μ-SCH2Ph)2(μ-dppm)2Cl2]; a single crystal X-ray diffraction analysis shows that all the palladium atoms in the compound are tetra-coordinated with distorted square-planar geometry, of which two are asymmetrically coordinated with selenium, sulfur, chlorine, and phosphorus atoms.
Original language | English |
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Pages (from-to) | 2083-2084 |
Number of pages | 2 |
Journal | Chemical Communications |
Issue number | 19 |
DOIs | |
Publication status | Published - 7 Oct 1998 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry