A novel polynuclear palladium(II) complex with asymmetric coordination of palladium atoms

Kong Cao, Weiping Su, Maochun Hong, Wenjian Zhang, Wing Tak Wong, Jiaxi Lu

Research output: Journal article publicationJournal articleAcademic researchpeer-review

10 Citations (Scopus)

Abstract

The oxidation of [Pd2(dppm)2Cl2] with selenium in the presence of NaSCH2Ph in DMF gives rise to a novel polynuclear complex [Pd4(μ3-Se)2(μ-SCH2Ph)2(μ-dppm)2Cl2]; a single crystal X-ray diffraction analysis shows that all the palladium atoms in the compound are tetra-coordinated with distorted square-planar geometry, of which two are asymmetrically coordinated with selenium, sulfur, chlorine, and phosphorus atoms.
Original languageEnglish
Pages (from-to)2083-2084
Number of pages2
JournalChemical Communications
Issue number19
DOIs
Publication statusPublished - 7 Oct 1998
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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